Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
=Chemical Properties.=—The atomic weight of copper is 63·57. The metal
is unchanged in dry air at ordinary temperatures; in the presence of
moisture and of carbon dioxide a green coating of basic carbonate is
produced. When heated in air, a black scale, consisting of cuprous
oxide, Cu_{2}O, is obtained, which is readily detached by quenching
and hammering. Water at ordinary temperatures is without effect upon
copper; concentrated sulphuric and nitric acids have little action
upon it in the cold, but attack it on heating. The best solvent for
the metal is dilute nitric acid, which dissolves it very readily.
Copper is liable to corrosion when subjected, whilst hot, to the
action of chlorine or hydrochloric acid gas; this action has provided
an explanation of the corrosion of copper boiler tubes where the coal
employed had been exposed to sea water.
Copper is deposited from solution as a dull red, spongy mass, by iron,
zinc, or aluminium, but it is more electro-positive than gold or
silver, and readily precipitates these metals from solutions of their
salts, these effects being extensively made use of in practice. The
metal possesses a powerful affinity for sulphur, and this property has
very important applications in the smelting processes.
Copper readily alloys with gold, silver, tin, zinc, and nickel, but not
with lead or iron.
References.
Composition and Properties of Metal for Railway and Locomotive Work
(p. 20).
_Proc. Inst. Mech. Eng._, 1893; Dean, p. 139; Blount, p. 164;
Watson, p. 168; Gowland, p. 176; Aspinall, p. 193;
Tomlinson, p. 182.
Webb, F. W., “Locomotive Fire-box Stays.” _Proc. Inst. C.E._, 1902.
Milton, J. T., “The Treatment of Copper for Steam Pipes.”
_Inst. Marine Eng._, 1908–9.
Hughes, G., “Non-ferrous Metals in Railway Work.”
_J. Inst. Metals_, Sept. 1911.
Law, E. F, “Alloys.”
Influence of Impurities on the Electrical Conductivity of Copper
(p. 24).
Public-domain text, read in full here on John Shaqi.
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