Nitro-Explosives: A Practical Treatise — John Shaqi
Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
Nitro-glycerine has a sweet taste, and causes great depression and
vertigo. It is soluble in ether, chloroform, benzene, glacial acetic acid,
and nitro-benzene, in 1.75 part of methylated spirit, very nearly
insoluble in water, and practically insoluble in carbon bisulphide. Its
formula is C_{3}H_{5}(NO_{3})_{3}, and molecular weight 227. When pure, it
may be kept any length of time without decomposition. Berthelot kept a
sample for ten years, and Mr G. M'Roberts, of the Ardeer Factory, for nine
years, without their showing signs of decomposition; but if it should
contain the smallest trace of free acid, decomposition is certain to be
started before long. This will generally show itself by the formation of
little green spots in the gelatine compounds, or a green ring upon the
surface of liquid nitro-glycerine. Sunlight will often cause it to
explode; in fact, a bucket containing some water that had been used to
wash nitro-glycerine, and had been left standing in the sun, has in our
experience been known to explode with considerable force. Nitro-glycerine
when pure is quite stable at ordinary temperatures, and samples have been
kept for years without any trace of decomposition. It is very susceptible
to heat, and even when quite pure will not stand a temperature of 100 deg. C.
for a longer period than a few hours, without undergoing decomposition. Up
to a temperature of 45 deg. C., however, properly made and purified nitro-
glycerine will remain unchanged almost indefinitely. The percentage
composition of nitroglycerine is as follows:--
Found. Theory for C_{3}H_{5}(N0_{2})_{3}.
Carbon 15.62 15.86 per cent.
Hydrogen 2.40 2.20 "
Nitrogen 17.90 18.50 "
Oxygen ... 63.44 "
The above analysis is by Beckerheim. Sauer and Adou give the nitrogen as
18.35 to 10.54 per cent. by Dumas' method; but I have never found any
difficulty in obtaining percentages as high as 18.46 by the use of Lunge's
nitrometer. The decomposition products by explosion are shown by the
following equation--
2C_{3}H_{5}(NO_{3})_{3} = 6CO_{2} + 5H_{2}O + 6N + O;
that is, it contains an excess of 3.52 per cent. of oxygen above that
required for complete combustion; 100 grms. would be converted into--
Carbonic Acid (CO_{2}) 58.15 per cent.
Water 19.83 "
Oxygen 3.52 per cent.
Nitrogen 18.50 "
The volume of gases produced at 0 deg. and 760 mm., calculated from the above,
is 714 litres per kilo, the water being taken as gaseous. Nitro-glycerine
is decomposed differently if it is ignited as dynamite (i.e., kieselguhr
dynamite), and if the gases are allowed to escape freely under a pressure
nearly equal to that of the atmosphere. Sarrau and Vieille obtained under
these conditions, for 100 volumes of gas--
NO 48.2 per cent.
CO 35.9 "
CO_{2} 12.7 "
H 1.6 per cent.
N 1.3 "
CH_{4} 0.3 "
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