Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
These conditions are similar to those under which a mining charge, simply
ignited by the cap, burns away slowly under a low pressure (i.e., a miss
fire). In a recent communication, P.F. Chalon (_Engineering and Mining
Journal_, 1892) says, that in practice nitro-glycerine vapour, carbon
monoxide, and nitrous oxide, are also produced as the result of
detonation, but he attributes their formation to the use of a too feeble
detonator.
Nitro-glycerine explodes very violently by concussion. It may be burned in
an open vessel, but if heated above 250 deg. C. it explodes. Professor C.E.
Munroe gives the firing point as 2O3 deg.-2O5 deg. C., and L. de Bruyn[A] states
its boiling point as 185 deg.. He used the apparatus devised by Horsley. The
heat of formation of nitro-glycerine, as deduced from the heat of
combustion by M. Longuinine, is 432 calories for 1 grm.; and the heat of
combustion equals 1,576 cals. for 1 grm. In the case of nitro-glycerine
the heat of total combustion and the heat of complete decomposition are
interchangeable terms, since it contains an excess of oxygen. According to
Dr W.H. Perkin, F.R.S.,[B] the magnetic rotation of nitro-gylcerine is
5,407, and that of tri-methylene nitrate, 4.769 (diff. = .638). Dr Perkin
says: "Had nitro-glycerine contained its nitrogen in any other combination
with oxygen than as -O-NO_{2}, as it might if its constitution had been
represented as C_{3}H_{2}(NO_{2})_{3}(OH)_{3}, the rotation when compared
with propyl nitrate (4.085) would be abnormal."
[Footnote A: _Jour. Soc. Chem. Ind._, June 1896, p. 471.]
[Footnote B: _Jour. Chem. Soc._, W.H. Perkin, 1889, p. 726.]
The solubility of nitro-glycerine in various solvents has been
investigated by A.H. Elliot; his results may be summarised as follows:--
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