Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
It is very convenient to have a large copper water oven, containing a lot
of small separate compartments, large enough to hold about a handful of
the cotton, and each compartment numbered, and corresponding to one of the
drying cylinders. The whole apparatus should be fixed against the wall of
the laboratory, and may be heated by bringing a small steam pipe from the
boiler-house. It is useful to have a series of copper trays, about 3
inches by 6 inches, numbered to correspond to the divisions in the steam
oven, and exactly fitting them. These trays can then be taken by a boy to
the drying cylinders, and a handful of the cotton from each placed in
them, and afterwards brought to the laboratory and weighed (a boy can do
this very well), placed in their respective divisions of the oven, and
left for one to one and a half hours, and re-weighed.
When the cotton is found to be dry the bottom of the drying cylinder is
removed, and the cotton pushed out from the top by means of a piece of
flat wood fixed on a broom-handle. It is then packed away in galvanised-
iron air-tight cases, and is ready for the next operation. At some works
the cotton is dried upon shelves in a drying house through which hot air
circulates, the shelves being of canvas or of brass wire netting. The hot
air must pass under the shelves and through the cotton, or the process
will be a very slow one.
~Dipping and Steeping.~--The dry cotton has now to be nitrated. This is
done by dipping it into a mixture of nitric and sulphuric acids. The acids
used must be strong, that is, the nitric acid must be at least of a
gravity of 1.53 to 1.52, and should contain as little nitric oxide as
possible. The sulphuric acid must have a specific gravity of 1.84 at 15 deg.
C., and contain about 97 per cent. of the mono-hydrate (H_{2}SO_{4}). In
fact, the strongest acids obtainable should be used when the product
required is gun-cotton, i.e., the highest nitrate.
The sulphuric acid takes no part in the chemical reaction involved, but is
necessary in order to combine with the water that is liberated in the
reaction, and thus to maintain the strength of the nitric acid. The
reaction which takes place is the following:--
2(C_{6}H_{10}O_{5}) + 6HNO_{3} = C_{12}H_{14}(NO_{3})_{6} + 6 H_{2}O.
324 378 = 594 108.
Cellulose. Gun-Cotton.
Theoretically,[A] therefore, 1 part of cellulose should form 1.8 part of
gun-cotton. Practically, however, this is never obtained, and 1.6 lb. from
1 lb. of cellulose is very good working. The mixture of acids used is
generally 1 to 3, or 25 per cent. nitric acid to 75 per cent. sulphuric
acid.
[Footnote A: (594 x 1)/324= 1.83.]
[Illustration: FIG. 11.--TANK FOR DIPPING COTTON.]
[Illustration: FIG. 12.--THE COOLING PITS.]
Public-domain text, read in full here on John Shaqi.
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