He adds further: “To facilitate the formation of blue indigo in the
interior of the fabrics, the stuff to be dyed may be previously
impregnated by a saline solution, which has the property of
precipitating the white indigo from the alkaline solution, and of
fixing itself more rapidly upon the tissue. Oxide of copper and oxide
of manganese possess these properties in a high degree, and are used
in many establishments to hasten the dyeing process, and produce an
economy in raw materials. The pieces of cloth are placed in a solution
of sulphate of copper, in the proportion of 15 to 20 grams to the
litre (2.11 pints), and lightly thickened with starch. The fabrics,
thus impregnated by a kind of mordant, before receiving the blue dye
are first passed through a weak bath of milk of lime, which fixes the
oxide of copper upon the tissue. The blues thus obtained are more
intense, and have a peculiar lustre. This process is used in Austria
and Germany, where cotton fabrics are printed on both sides of the
tissue.”
Coming to the English authorities, Dr. Grace Calvert, in his recent
lectures before the Society of Arts, speaking of the cold vat for
dyeing cotton, says: “The oldest, and still most generally employed
method of preparing cold vats, consists of putting into a vat
containing about 2000 gallons of water 60 lbs. of indigo, very finely
powdered, 180 lbs. of slacked lime, and 120 lbs. of sulphate of
protoxide of iron, or green vitriol (free from any trace of copper
salt), the two latter substances being added from time to time. The
greater part of the lime used unites with the sulphuric acid of the
iron salt, to produce sulphate of lime or gypsum; and the liberated
protoxide of iron removes the oxygen from the indigo, becoming
converted into saline oxide, whilst the reduced indigo dissolves in
the excess of lime employed.”
He adds the following facts, which may be of practical value:—
“Messrs. R. Schloesser & Co., of Manchester, have introduced within
the last year or two a marked improvement, in the preparation of cold
vats, which removes the great objections of the bulky precipitate of
sulphate of lime, the formation of an oxide of iron, and the loss of
indigo by its combination with the oxide of iron. The bath remaining
much more fluid, the pieces are less apt to be spotted, and a better
class of work is produced. To carry out their process, they add to the
ordinary 2,000 gallon vat 20 lbs. of ground indigo, 30 lbs. of iron
borings, 30 lbs. of _their remarkable powdered zinc_, and 35 lbs. of
quicklime; the whole is stirred up from time to time, for twenty-four
hours, when it is ready for use. If the bath is not considered
sufficiently strong, a little more lime and zinc are introduced. The
chemical theory of the process is, that the zinc, under the influence
of the lime, decomposes the water, combining with its oxygen, and the
hydrogen thus liberated removes oxygen from the indigo which then
dissolves in the lime.”
Public-domain text, read in full here on John Shaqi.
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