After this lapse of time, the bath will be found covered with an
abundant froth and a very marked copper-colored pellicle; the veins
which float upon its surface are larger and more marked than they were
previously; the liquor becomes of a deep yellowish-red color. On
dipping the rake into the bath, and allowing the liquid to run off at
the edge, its color, if viewed against the light, is of a strongly
marked emerald-green, which gradually disappears, in proportion as the
indigo absorbs oxygen, and leaves in its place a mere drop rendered
opaque by the blue color of the indigo. The odor of the vat at this
instant is strongly ammoniacal; we also find in it the peculiar scent
of the pastel. When we discover a marked character of this kind in the
newly formed vat, we may without fear plunge in the stuff intended to
be dyed; but the tints given during the first working of the vat are
never so brilliant as those subsequently formed; this is owing to the
yellow-coloring matters of the pastel, which, aided by the heat,
become fixed on the wool at the same time as the indigo, and thus give
to it a greenish tint. This accident is common both with the pastel
and the woad vats; it is, however, less marked in the latter.
When the stuff or cloth has been immersed for an hour in the vat it
should be withdrawn; it would, in fact, be useless to leave it there
for a longer time, inasmuch as it could absorb no more of the coloring
principle. It is therefore to be taken from the bath and hung up to
dry, when the indigo, by attracting oxygen, will become insoluble and
acquire a blue color. Then we may replunge the stuff in the vat, and
the shade will immediately assume a deeper tint, owing to renewed
absorption of indigo by the wool. By repeating these operations, we
succeed in giving very deep shades. We must not, however, imagine that
the cloth seizes only on that portion of indigo contained in the
liquor required to soak it. Far from such being the case, experience
shows that, during its stay in the bath, it appropriates to itself,
within certain limits, a gradually increasing quantity of indigo. We
have here, then, an action of affinity, or perhaps a consequence of
porosity on the part of the wool itself.
Public-domain text, read in full here on John Shaqi.
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