The signs above described announce, in a most indubitable manner, that
fermentation is established, and that the vat has now the power of
furnishing to the indigo the hydrogen which is required to render it
soluble,—that contained in the pastel having been already taken up;
this, then, is the proper moment for adding the indigo, which should
be previously ground in a mill.
We stated above that the liquor of the vat should be previously
charged with a certain quantity of lime; we also find in it ammonia
generated by the pastel; but a part of these alkalies become saturated
by the carbonic acid gas along with the proper acids of the madder and
of the weld, as well as by the lactic acid produced by the bran during
fermentation. The ordinary guide of the dyer is the odor, which,
according to circumstances; becomes more or less ammoniacal. The vat
is said to be either soft or harsh; if soft, a little more lime should
be added to it. The fresh vat is always soft; it exhales a feeble
ammoniacal odor accompanied with the peculiar smell of the pastel; we
must, therefore, add lime to it along with the indigo; we usually
employ from five to six pounds, and, after having stirred the vat, it
is to be covered over. The indigo, being incapable of solution except
by its combination with hydrogen, gives no sign of being dissolved
until it has remained a certain time in the bath. We may remark that
the hard indigoes, as those of Java, require at least eight or nine
hours, whilst those of Bengal do not need more than six hours, for
their solution. We should examine the vat again three hours after
adding the indigo. We ordinarily remark that the odor is by this time
weakened; we must now add a further quantity of lime, sometimes less,
but generally about equal in amount to the first portion; it is then
to be covered over again, and set aside for three hours.
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