Consider, for example, the decay of potassium-40 into calcium-40.
Measuring this process is perfectly suitable from the point of view of
half-life, but the daughter product is identical with the most common
isotope of ordinary calcium. And calcium is present everywhere in
nature! Even the purest mineral of potassium, sylvite (the salt,
potassium chloride), contains so much calcium impurity that the
RADIOGENIC daughter calcium, produced by the decay of potassium in
geologic time, is negligible in comparison. We can say that the bottom
of this potassium-40 hourglass has been stuffed with so much sand from
the very beginning that the few grains that fall through the waist are
lost in the overall mass. This demonstrates that schemes involving the
decay of a relatively rare nuclide into a relatively common one are not
usable. Natural geochemical separations of elements are never perfect,
anyway.
Similarly, the decay of any of the RARE EARTH elements into other rare
earth elements is not particularly helpful, because the rare earths are
so similar chemically they tend to travel together when they move in
nature.[13] Wherever the parent isotope goes, the daughter tags along.
The Rubidium-Strontium Clock
The decay of rubidium-87 (⁸⁷Rb) into strontium-87 (⁸⁷Sr) is perhaps the
most useful scheme for geologic age determination. The same problem
shows up here, but at least there is a way out of the wilderness. It is
not exactly simple, but a consideration of it is fundamental to
understanding the process of nuclear dating. The figure shows patterns
from mass spectrometer charts; each peak represents an isotope of
strontium, and the height of every peak is proportional to the relative
abundance of that isotope. In the figure, A shows the mass-spectrum of a
rock or mineral containing COMMON strontium (which is a mixture of
several isotopes). The peak of ⁸⁷Sr is small compared to the others. B
shows the mass-spectrum of strontium from an old rubidium-rich mineral
CRYSTAL, drawn to the same scale, as far as the nonradiogenic isotopes,
⁸⁴Sr, ⁸⁶Sr, and ⁸⁸Sr, are concerned. The ⁸⁷Sr peak in this spectrum is
obviously larger than in the common strontium in A. This is because this
isotope is radiogenic and has been accumulating from the decay of
rubidium since this crystal was formed.
The question we must answer is: How much of this ⁸⁷Sr was formed from
⁸⁷Rb decay and how much originally was present in the crystal as an
impurity? If the amount of this ORIGINAL strontium is not too large, the
problem can be solved by simple arithmetic.
Public-domain text, read in full here on John Shaqi.
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