First, we must find a good sample of common strontium—that is, ordinary
strontium, the kind shown at left in the figure. We cannot require that
this strontium be entirely uncontaminated by radiogenic strontium,
because all strontium is more or less contaminated. What we need is
strontium contaminated to _just the same extent_ as the strontium that
was taken as an impurity into the closed system when it first formed. In
geological specimens such a material is usually available.
[Illustration: _Drawings of mass-spectrometer charts showing the
isotopic spectra of two kinds of strontium: (A) common strontium and (B)
strontium from an old mineral rich in rubidium._ (_See page 32 for photo
of a mass spectrometer._)]
[Illustration: _Rubidium-87 and strontium-87 fall on the same spot in
the mass spectrum. Therefore, rubidium must be separated chemically from
strontium before the strontium can be analyzed in a mass spectrometer.
It is done with ion-exchange columns. Four of them are shown in this
photograph. The author of this booklet is adding a sample, dissolved in
a few drops of hydrochloric acid, to the second column._]
Let us take as our closed system a mica crystal in a mass of granite.
Mica contains a fair amount of rubidium, and it retains its radiogenic
strontium very well. Furthermore, mica crystals are often associated or
even intergrown with the slender, rod-shaped crystals of a mineral
called apatite—a phosphate of calcium. It is justifiable, on the basis
of geological knowledge, to say that the mica and the apatite grew at
roughly the same time and thus presumably from the same liquid medium
that became granite when it later solidified. Now strontium is
geochemically similar to calcium, and some strontium will have gone into
the apatite crystal in place of calcium. Apatite contains no
alkalis—hence apatite will have virtually no rubidium (which is an
alkali) in it to contaminate the ⁸⁷Sr. Consequently, when we find
apatite in an old granite, we know the apatite will still contain the
kind of common strontium that was taken into the mica crystal when it
grew originally.
We can separate the apatite from the granite by standard mineralogical
techniques, extract the strontium from the apatite chemically, and
analyze it on a mass spectrometer to obtain the isotopic spectrum—the
relative amount of each isotope that is present. We can then perform the
same isotopic analysis on the strontium extracted from the mica, and
subtract the original (apatite) strontium from the total (mica)
strontium, to obtain the radiogenic component or daughter product. (See
page 32 for details of this method.)
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account