Obviously, there is a certain error associated with every isotopic
analysis, so such a calculation is meaningful only when the radiogenic
component is large compared with the error in the measurement of
isotopic abundance. When one large quantity must be subtracted from
another large quantity to obtain a small difference, there is an obvious
limit to how much one can trust the result. The absolute accuracy in
measuring strontium isotope abundance is a few tenths of 1%, using the
best mass spectrometers now available. In practice, one can trust a
calculated age for a specimen only when the ⁸⁷Sr is as little as about
5% radiogenic. The results do not mean much when only 1 or 2% is
radiogenic.
[Illustration: _A sample of granite being made ready for crushing and
mineral separation._]
The Uranium Fission Clock
When a neutron strikes the nucleus of uranium-235 (²³⁵U) or
plutonium-239 (²³⁹Pu), it may cause the nucleus to split into two
roughly equal fragments, releasing neutrons and energy. This is the
well-known process of neutron-induced fission, the method in which
nuclear energy is produced in both reactors and bombs.[14] The most
common uranium isotope, ²³⁸U, also breaks up by fission, but does so all
by itself, without the need for any external neutrons. That process is
_spontaneous fission_ and it goes on at random, very much like
radioactive decay. It is a relatively rare process and the fission
half-life is long—about 10 million aeons (10¹⁶ years). That means that
only about one spontaneous fission occurs in uranium-238 for every 2
million alpha decays. That is enough to make a useful clock, however,
because ²³⁸U is present almost everywhere. (See Table III on page 19.)
Imagine an atom of ²³⁸U in some mineral. When the atom suddenly
fissions, it breaks in two with considerable energy, and the two fission
fragments rip like cannon balls through the surrounding crystalline
structure in opposite directions, creating havoc along the way. They
travel a distance something like 10 microns (4 millionths of an inch)
before they are finally slowed down and stopped by all their collisions
with other atoms. Each fragment’s path remains behind as an intensely
damaged tube through the crystal.
The process was known for a long time before anyone was able to find
these fission tracks (the damaged tubes) in the crystals. Finally, about
1960, three young physicists, R. L. Fleischer, P. B. Price, and R. M.
Walker, working at the General Electric Research Laboratory, fell upon
the idea of etching freshly broken surfaces of crystals with acid. They
reasoned that a region so intensely disturbed by the passage of a
fission fragment should be etched more easily and deeply than the
undisturbed surrounding crystal. That idea turned out to be correct, and
fission tracks have now been found in almost every common mineral (since
almost all minerals contain small amounts of uranium).
Public-domain text, read in full here on John Shaqi.
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