On adipocire, and its formationWetherill, Charles Mayer
Science
On adipocire, and its formation
Wetherill, Charles Mayer
Adipocere; Fatty acids; Postmortem changes
The magnesia salts from which the fats (_c_) and (_d_) were separated,
gave as follows:—(_c_) 0·227 gave 0·01675 = 7·38 per cent. magnesia;
and (_d_) 0·1735 gave 0·012 = 6·92 magnesia. On comparing the melting
points of these fats, and making allowance for want of a more perfect
separation from impurities, there can be little doubt that they are
neutral palmitates of magnesia, as was before ascertained. According
to Heintz (Zoochemie, p. 1072,) stearic acid is C_{36}, H_{36},
O_{4}, and the magnesia salt contains by calculation, 6·9 per cent.
of that base. The foregoing experiments upon the two specimens of
human adipocire were intended preliminary to a more thorough research
into their nature, by Heintz’s method; but this process requires such
a large quantity of substance in order to effect the separation of
small quantities of whatever new acid might be present, and the amount
of material dwindled so in the many necessary crystallizations from
alcohol to separate the dark-coloured impurities, and especially, since
the determinations and reactions already made, were so confirmatory
of what has lately been done in working upon the solid fatty acids,
I preferred placing aside the substances thus obtained for a future
examination, when the separation of fatty acids shall have become more
simplified, as it must be before long.
(_c_) _Fossil adipocire of Bison Americanus obtained from a metacarpal
bone from Big Bone Lick, by Dr. Leidy._--It was a white powder, and
in pulverizable lumps; amorphous under the microscope; with a talcose
feel, and of density a little below 0·8365, since it barely swims upon
alcohol of that strength, while it sinks in absolute alcohol. Water
will not wet it; with the addition of hydrochloric acid and heat, it is
separated without effervescence, into a mineral solution, and into an
oil which solidifies on cooling to a nearly white fat, a small portion
of which melted on a glass slide solidifies to a confusedly crystalline
mass; a small quantity treated in the same way with absolute alcohol,
crystallizes in plumose and dendritic crystals, like margaric acid.
A portion of the adipocire boiled with absolute alcohol, yields but
a minute quantity to the solvent, and that not of a fatty nature,
showing that the fatty acid is wholly saponified with an earthy base.
The whole quantity of adipocire weighed 0·986 grammes. 0·16325 heated
in a platinum crucible, fuses, burning with a smoky flame and with the
smell of fatty acid, but no acroleine, leaving 0·0165 or 10·1 per cent.
of a perfectly white ash, which hydrochloric acid almost perfectly
dissolves without effervescence, and which consists almost entirely of
lime, with a few minute specks of oxide of iron (seen during the action
of the hydrochloric acid,) and a couple of small grains of sand: there
is a very small trace of phosphoric acid present. The greater portion
of the adipocire, 0·716 grammes, was decomposed by hydrochloric acid
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