On adipocire, and its formationWetherill, Charles Mayer
Science
On adipocire, and its formation
Wetherill, Charles Mayer
Adipocere; Fatty acids; Postmortem changes
[Transcribers note: Missing text.]precipitate the whole, was added; to the
filtrate an excess of the magnesia solution was added, and the fat
remaining in the filtrate from this precipitation was separated, as
was also that of the other two precipitates. The following results and
melting points are in their order as determined:
(_a_) 0·351 melts 61°
(_b_) 0·527 melts 61°
(_c_) 0·085 melts 53°
loss 0·173
—————
1.136 grammes.
(_a_) and (_b_) were united, dissolved in alcohol, enough alcoholic
solution of acetate of magnesia to precipitate the half added, and
after standing for a couple of days, the precipitate was filtered off,
and ammonia added to alkaline reaction to the filtrate. The first
magnesia salt was translucent, and fused by heat to a transparent
liquid, which by more heat gradually grew darker, finally black, and
left a residue of magnesia. The melting point of the fat of this
substance was as before, 61°.
The second magnesia salt was white and amorphous; it presented the same
relations to heat as the first, and contained a fat of the same melting
point, 61°. These fats were both brilliant white, lamellar, and of
rough surface. The first magnesia salt contained a per centage of 7·59
MgO (0·25025 gave 0·019) and the second contained about double the per
centage of magnesia, viz.: 14·91; for 0·28 salt gave 0·04175 magnesia
by incineration.
Neutral palmitate of magnesia C_{32}, H_{31}, O_{3} MgO gives by
calculation 7·6 per cent. magnesia, and basic palmitate C_{32}, H_{31},
O_{3} 2 MgO gives 14·15 magnesia, which approaches the nearest to the
magnesia salt of the above fatty acids.
The experiments of fractional precipitation of the normal solution
of fat 6°, were conducted in the same manner, and with the following
results, in which (_c_) and (_d_) represent the fatty acids of the two
magnesia salts, and (_e_) that of the portion not precipitated by an
excess of acetate of magnesia:
(_c_) 0·474 melt pt. 59.5°
(_d_) 0·440 melt pt. 61.5°
(_e_) 0·356 melt pt. 58.5°
loss during the ex. 0·010
—————
1·280 grammes of fat.
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