On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
M. Bunsen detected the characteristic crimson lithium line in the
spectra of numerous substances; in granite, in the earliest geological
strata, in meteoric stones, in the ashes of most land plants, in blood
and other animal matter; so that instead of being one of the rarest
metals, it exists in all the three kingdoms of nature. In the year 1857
Mr. Swan gave an instance of the extreme minuteness of spectrum
analysis, by detecting the 1/2,300,000th part of a grain of salt by its
yellow light; but by the same reaction M. Bunsen not only recognised the
180 millionth part of a grain of sodium, but found that there is hardly
any substance that does not contain it. It exists in the dust on our
clothes and furniture, particles of it float in the air we breathe, so
that while examining the spectra of other incandescent substances,
flashes of yellow light appear as these atoms are volatilized and
instantly burnt up, which shows that common salt is perhaps more
universally diffused than any other kind of matter.
By spectrum analysis, M. Bunsen has discovered the two new metals,
rubidium and cæsium. While examining with a prism the spectrum of the
hundredth part of a grain of an alkaline substance separated from the
residuum of the Durckheim mineral water, he saw coloured lines, which he
had never seen before on the spectrum of any other alkali, and at once
concluded that they belonged to a new metal; and having obtained about
200 grains of the substance by the evaporation of forty tons of the
water, he found that they contained the chlorides of the two new metals
in question. Moreover he perceived that these metallic chlorides
resemble the chloride of potassium so nearly in spectrum and chemical
character, that a refined prismatic analysis could alone determine the
difference. He thus ascertained that the spectra of all the three have
two red lines in the red part of their spectrum, and two violet lines in
the indigo, while the middle part is occupied by a continuous diffused
light. The only difference is that the two red lines in the rubidium
spectrum are less refrangible than the red lines in the potassium
spectrum, and that the cæsium spectrum is distinguished by two bright
blue lines in the diffuse middle part. Rubidium received its name from
rubidus, on account of the dark red of its lines, and cæsium from its
sky-coloured blue lines.
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