On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Melloni had investigated the laws of the radiation and absorption of
radiant heat in solid and liquid matter; but its radiation and
absorption by gases and vapours was unknown previous to the experiments
of Mr. Tyndall.
The apparatus employed was a horizontal brass tube four feet long,
between two and three inches in diameter, polished inside, and closed
air-tight at each end by a plate of rock-salt, which transmits more heat
than any other substance. The air could be pumped out of the tube by one
pipe, and the gas or vapour for the experiment introduced by another.
Close to one end of the brass tube there was a thermo-electric pile
connected with its goniometer. On each side of this arrangement there
was a vessel of water kept at the boiling point. These two vessels were
so placed that when the rays of heat from one of them passed through the
exhausted tube, and fell upon one face of the thermo-electric pile,
their effect was so neutralized or balanced by the rays of heat falling
on the opposite face of the pile from the other, thus the needle of the
goniometer was steadily maintained at zero, and its deflection instantly
showed the absorbent effect produced by any gas or vapour that was
admitted into the exhausted tube.
Since aqueous vapour has a very exalted absorbent power, a gas or vapour
was rendered perfectly dry before its absorbent capacity was determined.
For that purpose the pipe that introduced it into the brass experimental
tube was so constructed that the gas had first to pass over fragments of
pumice-stone wet with strong sulphuric acid, which absorbed its moisture
and dried it. Common atmospheric air, however, was not only dried in
this manner, but it was deprived of its carbonic acid by passing over
caustic potash, and many other precautions were taken to prevent the
possibility of error.
Under the ordinary pressure of the atmosphere, when the experimental
tube was exhausted, the needle of the goniometer stood at zero, but as
soon as pure dry atmospheric air was introduced into the tube its
absorption caused the needle to move from zero to 1°.
Public-domain text, read in full here on John Shaqi.
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