On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The tube was again exhausted; the needle stood at zero, but was
deflected from zero to 1° as soon as the tube was filled with oxygen. A
similar experiment was made with nitrogen and hydrogen with the same
result. Thus, dry air and the elementary gases, oxygen, nitrogen, and
hydrogen, have the same absorptive power, and consequently they all
deflected the needle of the goniometer one degree. The whole amount of
radiant heat that passed through the exhausted tube produced a
deflection of 71° 5ʹ; hence taking as unit of heat the amount that would
deflect the needle one degree, the number of units expressed by 71° 5ʹ
is 308, consequently the absorption of each of these four gases amounts
to 100/308 or 0·3 per cent. The most delicate tests could not show any
difference between the three first, but Professor Tyndall had reason to
believe that hydrogen has the lowest absorptive power of all gases and
vapours, though he was unable to express the amount. The absorptive
power of all four is very much less than that of every other gas or
vapour, and invariably deflects the needle to 1°, which thus becomes the
unit of comparison.
Olefiant gas, the most luminous of the constituents of coal gas,
possesses the highest absorptive power of the permanent gases. When sent
into the exhausted tube it deflected the needle of the goniometer from
0° to 70° 3ʹ, which is equivalent to 290 units. The whole heat that
passed through the exhausted tube before the gas was admitted produced a
deflection of 75° or 360 units, consequently more than 7/10ths or 81 per
cent. of the whole heat was cut off by the olefiant gas. Such opacity to
heat in so transparent a gas is quite marvellous. A current of it was
sent into the open air between the thermo-electric pile and one of the
sources of heat, and although it was perfectly invisible, it instantly
deflected the needle of the goniometer from 0° to 41°.
In order to ascertain the relation between the density of the gas and
the quantity of heat extinguished or absorbed, an ordinary mercurial
gauge was attached to the air-pump. The experimental tube was exhausted,
and the needle of the goniometer stood at zero. Then, from a graduated
glass vessel, measures of olefiant gas, each amounting to the 1/50th of
a cubic inch, were successively sent through the drying pipe into the
exhausted tube. The amount of the heat absorbed and the depression of
the mercurial column corresponding to each measure of gas as it was
introduced, was registered from one to fifteen measures. This experiment
showed that for very small quantities of gas, the absorption is exactly
proportional to the density or tension. One measure of the gas only
produced a depression of the mercurial column amounting to the 1/367th
part of an inch, or about the 1/15th of a millimetre.
Public-domain text, read in full here on John Shaqi.
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