On Molecular and Microscopic Science, Volume 1 (of 2) — John Shaqi
On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The effect produced by 1/30th of an inch of tension of air and the
elementary gases is equivalent to that produced by one inch in the
others, so the unit representing the absorption of these four gases is
only the 1/30th part of the unit in the preceding table.
It appears from the preceding tables of comparative absorption that
chlorine, a highly-coloured gas with a specific gravity of 2·45, has an
absorptive power expressed by 39° under the pressure of one atmosphere,
while, at the same tension, hydrochloric acid, a chemical compound of
chlorine and hydrogen which is perfectly transparent, with a specific
gravity of only 1·26, has an absorptive action amounting to 62, whence
it appears that the chemical change which renders chlorine more
transparent to light, makes it more opaque to obscure heat. Again,
bromine, which is far less permeable to light than chlorine, and has a
specific gravity of 5·54, has an absorptive power of 160 under a tension
of one inch; while hydrobromic acid, which is perfectly transparent to
light, has an absorptive action for obscure heat amounting to 1005. This
is a striking instance of transparency to light and opacity to heat
being produced by the very same chemical art.
The enormous difference between the absorptive power of compound and
simple gases and vapours is ascribed to their atomic structure; in fact
the radiant and absorptive powers augment as the number of atoms in the
compound molecule augments. The three elementary gases are formed of
simple atoms, the compound gases and vapours consist of different kinds
of atoms chemically united into groups. Both are free to receive the
vibratory motions of the ether which constitute heat; but single atoms
must produce a less effect than when a number of them are united into a
molecule. The atoms are loaded by their chemical union, which offers a
greater surface of resistance to the vibrations of heat, and renders the
motion of the molecule more sluggish and more fit to accept the slowly
recurrent waves of the obscure heat that strike upon it.
Thus when atoms of hydrogen and nitrogen are mixed in the proportion of
three to one, the absorption of the mixture is represented by unity; but
when they are chemically united in ammonia, the absorption is 1190 times
as great. Atoms of hydrogen and oxygen mixed in the proportion of two to
one absorb very feebly; when chemically united into a molecule of
aqueous vapour the absorptive power is enormous. The absorptive power of
nitrous oxide, a chemical compound of oxygen and nitrogen, exceeds that
of dry air 250 times; a convincing proof that the atmosphere is a
mixture and not a compound gas. Olefiant gas at five inches of tension
absorbs 1000 times that of its constituent hydrogen. In fact all the
compound gases and vapours far surpass the simple elementary gases and
dry atmospheric air in their capacity for absorption.
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