On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
In many of the vapours of volatile liquids, the preceding law only
prevails to a certain amount of pressure differing in each case, beyond
which increase of tension produces diminished effects. In sulphuric
ether the change begins at the eleventh term.
In bisulphide of carbon the law changes after the sixth measure, &c.
In order to adapt the apparatus for experiments on coloured gases, a
glass experimental tube 2 ft. 9 in. long, and 2 ft. 4 in. in diameter,
was substituted for the brass tube, and, instead of boiling water,
sources of radiant heat having a constant temperature of 270° Cent. were
adopted.
The following table shows the absorption of a number of gases at a
common pressure or tension of one atmosphere.
Dry air = 1
Oxygen 1
Nitrogen 1
Hydrogen 1
Chlorine 39
Hydrochloric acid 62
Carbonic oxide 90
Carbonic acid 90
Nitrous oxide 35·5
Sulphuretted hydrogen 390
Marsh gas 403
Sulphurous acid 710
Olefiant gas 970
Ammonia 1195
The absorptive power of ammonia is so great, that although as
transparent in the glass tube as if it had been a vacuum, a length of
three feet of it would be perfectly impervious or black to the heat here
employed, yet even this does not express the energy which it exhibits
under one inch of pressure.
When the relative absorptive actions of gases and vapours is compared,
it must be under the same amount of pressure. Hence, for one inch of
tension, the absorptive action of
Dry air = 1
Oxygen 1
Nitrogen 1
Hydrogen 1
Chlorine 60
Bromine 160
Hydrochloric acid 1005
Carbonic oxide 750
Nitric oxide 1590
Nitrous oxide 1860
Sulphide of hydrogen 2100
Ammonia 7260
Olefiant gas 7950
Sulphurous acid 8800
Thus, for a tension of an inch of mercury, the absorption of ammonia
exceeds that of air more than 7000 times; the action of olefiant gas is
7950 times, and that of sulphurous acid 8800 times, greater than the
absorption of air.
Public-domain text, read in full here on John Shaqi.
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