On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Carbonic oxide and carbonic acid are pervious to a vast majority of the
rays of radiant heat. When the cylinder was filled with carbonic oxide
gas and so divided, by moving the internal plate of rock-salt, that a
stratum of the gas 8 inches long was next to the source of heat, and
that 41·4 inches long farthest from it, the 8 inches of gas intercepted
6 per cent. of the whole radiation. But when the plate of rock-salt was
moved till the column 41·4 inches long was next to the source of heat,
and that of 8 inches farthest from that source, or behind the long one,
the absorption of the 8 inches was sensibly zero. In like manner eight
inches of carbonic acid gas when in front of a column of 41·4 inches of
the same gas absorbed 6-1/4 per cent. of the whole radiation, while
placed behind that column the effect was nearly zero. The reason is that
when the 8 inch stratum is in front, it stops the main portion of the
rays which give it its thermal colours,[7] while placed behind these
same rays have been almost wholly withdrawn, and to the remaining 94 per
cent. of the radiation the gases are sensibly permeable.
It is inferred from an extension of this reasoning that the sum of the
absorptions of the two chambers taken separately must always be greater
than the absorption effected by a single column of the gas of a length
equal to the sum of the two chambers; this conclusion is illustrated in
a striking manner by the experiments. It is also found that when the
mean of the sums of the absorptions is divided by the absorption of the
sum, the quotient is sensibly the same for all gases. It may farther be
inferred that the sum of the absorptions must diminish and approximate
to the absorption of the sum as the two chambers become more unequal in
length, and that the sum of the absorptions of the two chambers is a
maximum when the medial plate of rock-salt divides the long tube into
two equal parts.
When air enters an exhausted tube it is heated dynamically by the
collision of its particles on the sides of the tube as it rushes in to
fill the vacuum; and when the tube is exhausted again by the air pump,
chilling is produced by the application of a portion of the heat of the
air to generate vis viva. This dynamic principle occurred in some of the
experiments, and was dexterously adopted and applied to the solution of
a striking and unprecedented problem: ‘To determine the radiation and
absorption of gases and vapours _without any source of heat external to
the gaseous body itself_.’
Public-domain text, read in full here on John Shaqi.
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