On Molecular and Microscopic Science, Volume 1 (of 2) — John Shaqi
On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The two external sources of heat being therefore dispensed with in the
absorptive apparatus, the thermo-electric pile was presented to the cold
glass tube which was exhausted, and the needle of the goniometer stood
at zero. Nitrous acid on entering the exhausted tube became heated and
radiated its heat upon the adjacent face of the pile which deflected the
needle of the goniometer through 28° in the direction that indicates
absorption. As the heat of the gas became gradually exhausted, the
needle returned slowly to zero. The pump was now worked, the rarefied
gas in the tube was chilled, and the adjacent face of the pile gradually
poured its heat on the chilled tube till the temperature of the pile was
so much lowered, that the needle was deflected 20° on the negative side
of zero, that is on the side denoting radiation.
When olefiant gas entered the exhausted tube, the needle showed an
absorption of 67°, and when the gas was pumped out again, the needle
showed a radiation amounting to 41°. When the gas was then pumped out,
very dry atmospheric air was introduced into the tube,—the needle
pointed to 59° indicating absorption; and when it was pumped out again
the needle swung to nearly 40° on the other side of zero, indicating
radiation. Remembering that the radiation and absorption of dry air only
produce a deflection of 1°, it is evident that the preceding great
deflection of the needle is entirely owing to the action of the small
residue of olefiant gas that remained in the exhausted tube. In order to
ascertain how much the quantity of a gas or vapour might be reduced
before its action became insensible, the vapour of boracic ether, which
has the greatest absorptive energy, was chosen.
The mercurial gauge for measuring the pressure or tension of the vapour
already mentioned remained attached to the apparatus. When one-tenth of
an inch of the vapour of boracic ether was admitted into the exhausted
tube, the barometer stood at 30 inches: hence the tension of the vapour
within the tube was the 1/300th part of an atmosphere. Dynamically
heated by dry air the radiation of the vapour produced a deflection of
56°. Again the tube was exhausted to 0·2 of an inch and the quantity of
vapour was thereby reduced to 1/150th of its first amount; the needle
was allowed to come to zero, and the residue of the vapour produced a
deflection of 42°. The pump was again worked till a vacuum of 0·2 of an
inch was obtained, this residue containing of course the 1/150th of the
quantity of ether present in the tube; and on dynamically heating the
residue, its radiation produced a deflection of 20°.
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