On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The heat of the electric spark volatilizes the metals which form the
points of the conducting wires; and all volatilized metals give
characteristic spectra, both visible and chemical. The visible part
differs from that of the solar spectrum in being crossed by bright lines
instead of dark ones; but the number, intensity, and position of both
the visible and invisible lines change with each metal. The changes in
the invisible part under consideration may be readily observed by
throwing the spectra either on a fluorescent or collodion plate. For
example: in the spectrum from the spark between thallium points thrown
on the latter, Dr. Miller found that there were two strong groups of
lines in the least refrangible part of the spectrum; at a little
distance from these there were three groups, the two first less intense
than the third; several rows of feeble dots followed, and the chemical
spectrum terminated rather abruptly with four nearly equidistant groups.
This spectrum bears a resemblance to those of zinc and cadmium, less
strongly to that of lead. Dr. Miller found that the photographic spectra
of iron, cobalt, and nickel, also have a strong analogy, but that the
metals arsenic, antimony, and tin showed as great a difference in the
invisible as in the visible part of their spectrum.
The fluorescent spectra of seventeen metals were examined by Professor
Stokes of Cambridge; several of them showed luminous lines of
extraordinary strength, especially zinc, cadmium, magnesium, aluminium,
and lead, which in a spectrum not generally remarkable contains one line
surpassing perhaps all other metals in brilliancy. Some other metals
exhibit in certain parts of their spectra lines that are both bright and
numerous; on the whole some parts of the spectra are strong and
tolerably continuous, while in others they are weak. This grouping of
the lines is most remarkable in copper, nickel, cobalt, iron, and tin.
Of all the metals examined, magnesium gave the shortest spectrum, ending
in a very bright line, beyond which however excessively faint light
extended to a distance equal to that of the long spectra. Aluminium, on
the other hand exceeded all the other metals in richness of the rays of
the very highest refrangibility. All the strong lines mentioned lie in
that part of the spectra.
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