On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
In the course of these experiments Professor Stokes observed that even
quartz of a certain thickness is not transparent to invisible lines of
the highest refrangibility, for the highest aluminium line, which is
double, could only be seen by rays passing through the edge of the
prism. This leads to another branch of the subject, namely, the
absorption of the invisible rays by solids, liquids and gases. Mr. Wm.
Allen Miller has shown from his own experiments that bodies pervious to
the chemical rays in the solid form, are so also in the liquid and
gaseous form; that colourless transparent solids which absorb the
photographic rays, absorb them more or less also in their liquid and
gaseous states. He has moreover found that the following substances have
the same maximum transparency:—rock crystal, ice, and fluor spar among
solids, water among liquids, the three elementary gases and carbonic
acid among gaseous substances. The most opaque to the invisible rays
are, nitrate of potash, bisulphide of carbon, and sulphuretted hydrogen.
It appears that a thin plate of mica is intensely opaque to all the
invisible rays except a small portion of them of the lowest
refrangibility.
The absorptive property however is partial: an absorptive substance
either cuts off a portion of the light of a fluorescent spectrum or
stripes it with dark lines: each substance absorbs rays peculiar to
itself. Those employed by Professor Stokes were the alkaloids and
glucosides, and he assumed the spectrum of tin for their examination
because it has a long interval of continuity.
The fluorescent property of yellow uranite was discovered by Professor
Stokes some years ago, and now he has added another fluorescent mineral
in adularia or moonstone; from its natural faces and planes of cleavage
alike a beautiful blue fluorescence emanated under the induction spark.
As the same was observed in colourless felspars generally, Professor
Stokes concluded that fluorescence is an inherent property in the
silicate of alumina and potash constituting the crystal of moonstone.
The blue fluorescence extended to a very sensible though small depth
within the substance.
A particular variety of fluor spar found at Alston Moor in Cumberland,
which is very pale by transmitted light, shows a strong blue
fluorescence, and is eminently phosphorescent on exposure to the
electric spark. It is the same kind of crystal in which Sir David
Brewster originally discovered the property of fluorescence. On
presenting such a crystal to the spark passing between aluminium
terminals, besides the usual blue fluorescence, there was another of a
reddish colour extending not near so far into the crystal, produced by
the rays belonging to the strong lines of aluminium of extreme
refrangibility.
Public-domain text, read in full here on John Shaqi.
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