On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
The cube of fluor spar which showed these effects was externally
colourless to the depth of 1/20 of an inch; then came one or two strata
parallel to the faces of the cube showing the ruddy fluorescence, while
the blue fluorescence extended to a much greater depth and had a
stratified appearance. This crystal was eminently phosphorescent, its
blue phosphorescence being arranged in strata parallel to the face of
the cube like the blue fluorescence, but it was not perceptible beyond a
very moderate distance below the surface at which the exciting cause
entered, that cause being the photographic rays of extremely high
refrangibility of the electric spark—taken, as in all these experiments,
between the secondary terminals of an induction coil in connection with
the coatings of a Leyden jar, and refracted by quartz prisms.
Mr. Stokes has employed fluorescence as a means of tracing substances in
impure chemical solutions. When a pure fluorescent substance is examined
in a pure spectrum it is found that on passing from the extreme red to
the violet and beyond, the fluorescence commences at a certain point of
the spectrum, varying from one substance to another, and continues from
thence onwards more or less strongly in one part or another according to
the particular substance. The colour of the fluorescent light is found
to be nearly constant throughout the spectrum. ‘Hence when in a solution
examined in a pure spectrum we notice the fluorescence taking as it were
a fresh start _with a different colour_, we may be pretty sure that we
have to deal with a mixture of two fluorescent substances.’
Experience as well as theory shows that rapid absorption is accompanied
by copious fluorescence. But experience has hitherto also shown what
could not have been predicted, and may not be universally true, that
conversely absorption is accompanied in the case of a fluorescent
substance by fluorescence.
The phosphorescent light of insects, fish, and plants is owing to
chemical action, which produces many luminous phenomena; but a great
number of inorganic and organic substances shine in the dark with a
phosphorescence which is nearly allied to fluorescence. It is produced
by exposure to the sun, by heat, electricity, insulation, cleavage,
friction, and motion. For if a bottle containing nitrate of uranium be
shaken, it shines spontaneously with a vivid light; even the hand shows
phosphorescence in the dark after being exposed to the sun.
Public-domain text, read in full here on John Shaqi.
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