On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
It follows from the atomic theory that the number of atoms in equal
weights of any two solid substances, is in the inverse ratio to the
weights of these atoms. Now since the bodies that have the greatest
specific gravities are the heaviest, if the specific gravities and
atomic weights of equal bulks of two simple substances be known, the
relative number of atoms they contain may be found. For the density
divided by the atomic weight of the one, is to the density divided by
the atomic weight of the other, as the number of atoms in the first to
the number of atoms in the second. By the preceding law it is found that
in equal bulks of the three metals, sodium, platinum, and potassium,
platinum contains five times as many atoms as sodium, and ten times as
many as potassium. When substances which have strong analogous qualities
are compared in this manner, the results are either equality, or a
simple ratio.
It has already been mentioned that the protoxides of iron, copper, zinc,
nickel and manganese, have the same form, and contain the same quantity
of oxygen, but differ in the respective metals that are combined with
it; and by the preceding law it appears that equal bulks of these
isomorphous bodies contain also the same number of atoms.
Mr. Hermann Kopp has proved that the atomic weight of a substance
divided by the specific gravity, that is to say, its atomic volume, is
the same for all isomorphic bodies simple and compound, and as a general
law that the atoms of isomorphous substances are not only the same in
form, but equal in dimensions. It follows, therefore, that any one of
the preceding metals might be substituted for any other in the
respective protoxides, and on that account, according to the modern
theory, they are the chemical equivalents of each other, for that
expression is used now in a different sense from what it formerly had.
Chemical equivalency between two or more substances consists in their
capacity for being exchanged one for the other. Direct or indirect
substitution forms the basis of the modern doctrine of chemical
equivalents.
Substances which are capable of replacing one another in compounds, and
which are endowed with qualities mutually analogous, are said to be
isomeric. Many isomeric compounds are formed of the same materials, in
the same proportions, and yet differ essentially both in their physical
and chemical properties; whence M. Daniel observes, that a specific and
definite arrangement of the constituent molecules in space appears to be
no less essential to the individual constitution of bodies than a
certain proportion between their heterogeneous ingredients.
Public-domain text, read in full here on John Shaqi.
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