Soon after a description of the process resorted to by M. Foucault in
his excellent experiments was procured. It consists in decomposing an
alcoholic solution of ammonia and nitrate of silver by oil of cloves.
The preparation of the solutions and putting them in a proper state of
instability are very difficult, and the results by no means certain.
The silver is apt to be soft and easily rubbed off, or of a leaden
appearance. It is liable to become spotted from adherent particles of
the solutions used in its preparation, and often when dissolved off a
piece of glass with nitric acid leaves a reddish powder. Occasionally,
however, the process gives excellent results.
In the winter of 1861, M. Cimeg published his method of silvering
looking-glasses by tartrate of potash and soda (Rochelle salt). Since I
have made modifications in it fitting the silver for being polished on
the reverse side, I have never on any occasion failed to secure bright,
hard, and in every respect, perfect films.
The operation, which in many details resembles that of M. Foucault, is
divided into: 1st, cleaning the glass; 2d, preparing the solutions;
3d, warming the glass; 4th, immersion in the silver solution and stay
there; 5th, polishing. It should be carried on in a room warmed to
70° F. at least. The description is for a 15-1/2 inch mirror.
1st. Clean the glass like a plate for collodion photography. Rub it
thoroughly with nitric acid, and then wash it well in plenty of water,
and set it on edge on filtering paper to dry. Then cover it with a
mixture of alcohol and prepared chalk, and allow evaporation to take
place. Rub it in succession with many pieces of cotton flannel. This
leaves the surface almost chemically clean. Lately, instead of chalk I
have used plain uniodized collodion, and polished with a freshly-washed
piece of cotton flannel, as soon as the film had become semi-solid.
2d. Dissolve 560 grains of Rochelle salt in two or three ounces of
water and filter. Dissolve 800 grains of nitrate of silver in four
ounces of water. Take an ounce of strong ammonia of commerce, and add
nitrate solution to it until a brown precipitate remains undissolved.
Then add more ammonia and again nitrate of silver solution. This
alternate addition is to be carefully continued until the silver
solution is exhausted, when some of the brown precipitate should remain
in suspension. The mixture then contains an undissolved excess of
oxide of silver. Filter. Just before using, mix with the Rochelle salt
solution, and add water enough to make 22 ounces.
[Illustration: Fig. 1. The Silvering Vessel.]
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