Generally silvered mirrors are very enduring, and will bear polishing
repeatedly, if previously dried by heat. I have some which have been
used as diagonal reflectors in the Newtonian, and have been exposed
during a large part of the day to the heat of the sun concentrated by
the 15-1/2 inch mirror. These small mirrors are never covered, and yet
the one now in the telescope has been there a year, and has had the
dusty film--like that which accumulates on glass--polished off it a
dozen times.
In order to guard against tarnishing, experiments were at first made in
gilding silver films, but were abandoned when found to be unnecessary.
A partial conversion of the silver film into a golden one, when it will
resist sulphuretted hydrogen, can be accomplished as follows: Take
three grains of hyposulphite of soda, and dissolve it in an ounce of
water. Add to it slowly a solution in water of one grain of chloride of
gold. A lemon yellow liquid results, which eventually becomes clear.
Immerse the silvered glass in it for twenty-four hours. An exchange
will take place, and the film become yellowish. I have a piece of glass
prepared in this way which remains unhurt in a box, where other pieces
of plain silvered glass have changed some to yellow, some to blue, from
exposure to coal gas.
I have also used silvered glass plates for daguerreotyping. They iodize
beautifully if freshly polished, and owing probably to the absence
of the usual copper alloy of silver plating, take impressions with
very short exposures. The resulting picture has a rosy warmth, rarely
seen in ordinary daguerreotypes. The only precaution necessary is in
fixing to use an alcoholic solution of cyanide of potassium, instead of
hyposulphite of soda dissolved in water. The latter has a tendency to
split up the silver. The subsequent washing must be with diluted common
alcohol.
Pictures obtained by this method will bear high magnifying powers
without showing granulation. Unfortunately the exposure required for
them in the telescope is six times as great as for a sensitive wet
collodion, though the iodizing be carried to a lemon yellow, the
bromizing to a rose red, and the plate be returned to the iodine.
(3.) GRINDING AND POLISHING GLASS.
Some of the facts stated in the following paragraphs, the result of
numerous experiments, may not be new to practical opticians. I have
had, however, to polish with my own hands more than a hundred mirrors
of various sizes, from 19 inches to 1/4 of an inch in diameter, and to
experience very frequent failures for three years, before succeeding
in producing large surfaces with certainty and quickly. It is well
nigh impossible to obtain from opticians the practical minutiæ which
are essential, and which they conceal even from each other. The long
continued researches of Lord Rosse, Mr. Lassell, and M. Foucault are
full of the most valuable facts, and have been of continual use.
Public-domain text, read in full here on John Shaqi.
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