On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins UniversityKeiser, Edward Harrison
Science
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University
Keiser, Edward Harrison
Oxygen; Thesis (Ph. D.)
Clausius[3] at one time supposed that free atoms of oxygen might exist
in an uncombined state, and his hypothesis on the nature of ozone
was that this substance consisted of a mixture of molecules and free
atoms of oxygen. In a later paper[4], however, he abandoned this view
and regarded ozone as consisting of one or more atoms of oxygen feebly
united, (lose verbunden) with molecules of ordinary oxygen.
The idea that a third form of oxygen existed also obtained support from
the fact that certain organic substances when exposed to the light in
the presence of oxygen or air, acquire oxidizing properties. In 1850
Schönbein[5] stated that ether turpentine, and oil of lemons if allowed
to stand in diffused light in contact with the air acquires the
power of decomposing potassium iodide, and decolorizing indigo. In a
subsequent paper[6] he shows that methyl and ethyl alcohols, tartaric
and citric acids and even sulphuretted and arsenuretted hydrogen
in the presence of sun light can decolorize indigo. These studies
led Schönbein to publish a theory on the different modifications of
oxygen. In this paper[7] he states that besides ordinary oxygen there
are two other conditions in which it may exist one of these is ozone,
or positively electrified oxygen, the other _antozone_ or negatively
electrified oxygen. The union of ozone and antozone gives ordinary
oxygen. He also stated that antozone was formed by the action of light
on turpentine and air, and subsequently in 1862[8] he claimed that
antozone was identical with the gas obtained when barium superoxide
is treated with acids. Meissner[9] also supported the views of
Schönbein and claimed that antozone was formed in two ways:--1st, By
treating barium dioxide with concentrated sulphuric acid, 2nd, By the
electrification of oxygen; being produced simultaneously with the ozone.
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