On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins UniversityKeiser, Edward Harrison
Science
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University
Keiser, Edward Harrison
Oxygen; Thesis (Ph. D.)
These statements remained unquestioned for a number of years and are
found in the text books of the period, (for example Graham-Otto, and
Gorup-Besauez) but in 1870 Engler and Nasse[10] undertook a thorough
investigation to determine whether antozone existed. By treating
barium dioxide with strong sulphuric acid they find a gas to be given
off which is a mixture of ozone and hydrogen dioxide, and they also
show that the stronger the acid the greater the quantity of ozone
produced. Secondly, Meissner had stated that by the electrification of
oxygen ozone and antozone were formed. The evidence of the existence
of antozone being this; when the ozonized oxygen was passed through a
solution of potassium iodide to destroy the ozone, the residual gas
gave white fumes when brought into contact with water, and after a time
hydrogen dioxide could be detected in the water. Schönbein and Meissner
held that the ozone having been destroyed by the potassium iodide
the antozone passed on and oxidized the water to hydrogen dioxide.
Now Engler and Nasse show that when ozone is decomposed by easily
oxidisable substances in the presence of water hydrogen dioxide also is
formed, and it was the vapor of this compound which had been regarded
as antozone. It is known that ozone cannot oxidize water, but that it
is to a slight extent oxidized when other oxidisable substances are
present is not surprising, as other phenomena of a similar kind are
known. Thus when nitric acid acts on an alloy of silver with gold or
platinum, containing a certain proportion of silver, some of the gold
or platinum are dissolved although by themselves they are insoluble.
When ammonia burns some of the nitrogen as well as the hydrogen is
oxidized. Engler and Nasse therefore conclude that there is no basis
for the assumption of a third form of oxygen having the properties
attributed to antozone.
Berthelot[11] and Houzeau[12] conclude from their investigations that
the oxidizing properties which turpentine and other organic compounds
acquire under certain conditions is due to the formation of unstable
oxygenated compounds which readily decompose giving up oxygen.
Fudakowski[13] has described experiments showing that benzene can become
active, i.e. acquire oxidizing properties, but states that he is unable
to explain the phenomenon. Loew[14], however, believes active turpentine
to contain atomic oxygen or antozone in solution.
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