On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University — John Shaqi
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins UniversityKeiser, Edward Harrison
Science
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University
Keiser, Edward Harrison
Oxygen; Thesis (Ph. D.)
This theory has been taken up and developed by Baumann, who in 1881
published a paper[16] entitled “Contribution to the knowledge of Active
Oxygen.” The paper begins with the statement that besides ordinary
inactive oxygen and ozone there is a third modification known as
active or nascent oxygen. He states that this active oxygen cannot
be isolated, and its formation can only be recognized by its action
on other bodies. “Active oxygen (O) is the most powerful oxidizing
substance known and can unite with inactive oxygen (O_{2}) to form
ozone (O_{3}). The production of ozone is always preceded by the
formation of active oxygen,” but he states “active oxygen can be formed
under conditions when no ozone can be formed, this is the case when
easily oxidized substances are in contact with the active oxygen in
such a way that the latter is completely consumed in oxidizing those
substances.” “Thus, for instance, ozone is formed when oxygen is
rendered active by the slow combustion of moist phosphorus in air,
but no ozone is formed if the atmosphere surrounding the phosphorus
contains the vapor of alcohol, ether and similar substances.” The
fallacy of this reasoning becomes apparent on referring to the work of
Müller[17] on the luminosity of phosphorus who shows that substances
which prevent the luminosity also prevent its oxidation and if the
phosphorus is not oxidized we have no reason for assuming the formation
of active oxygen.
He then compares active oxygen with the antozone of Schönbein and says
that several of the properties of antozone can be ascribed to active
oxygen above all that property of antozone of oxidizing water to
hydrogen dioxide. The only difference between the two being that active
oxygen has but a momentary existence while antozone was supposed to be
capable of isolation.
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