On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins UniversityKeiser, Edward Harrison
Science
On the Existence of Active Oxygen: Thesis Presented for the Attainment of the Degree of Doctor of Philosophy at the Johns Hopkins University
Keiser, Edward Harrison
Oxygen; Thesis (Ph. D.)
After Engler and Nasse had demonstrated the nonexistence of antozone
all discussion on the subject ceased for a number of years, and it
was not until 1878 that Hoppe-Seyler[15] again opened the question. In
studying the processes of putrefaction he observed that free hydrogen
is given off in those cases in which oxygen is not present, and that
whenever oxygen has access to decaying liquids, not only is all the
hydrogen oxidized but energetic oxidation processes are observed as
well. The simplest explanation of this seemed to be that the nascent
hydrogen has the power of splitting up the oxygen molecule, uniting
with one atom and setting the other free, and these free atoms he
imagined brought about the strong oxidations which take place in
decaying bodies.
To test this hypothesis he made experiments with palladium hydrogen.
Graham has described the energetic reducing power of this compound but
that it can also cause oxidations Hoppe-Seyler showed by bringing some
strips of palladium charged with hydrogen into a solution of indigo
in the presence of air. The solution soon became yellow and after a
time the indigo was completely destroyed. If palladium hydrogen be
brought into a neutral solution of potassium iodide and starch, the
liquid becomes blue in a few minutes, after which the starch is slowly
destroyed. In a similar way benzene was oxidized to phenol. “These
experiments and others of a similar nature,” he asserts, “admit of no
explanation other than that the active hydrogen renders the oxygen
active, and since the former unites with oxygen we cannot well conceive
of the process without supposing that the hydrogen in uniting with one
atom of the molecule O_{2} sets the remaining atom free, thus making it
active.” “Just as the hydrogen atom cannot exist in a free state so the
active oxygen, if no oxidizable material is present, unites with water
to form hydrogen dioxide, or with inactive oxygen to form ozone.”
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