Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
[1] Alexander E. Outerbridge, Jr.: "A Novel Method of Detecting
Mineral Oil and Resin Oil in Other Oils." Proc. 14th Annual Meet.,
Amer. Soc. for Testing Mater., Atlantic City, N.J., June 28, 1911.
[Illustration: View of Stills Where Petroleum Paint Thinners are
Manufactured (Waverly)]
ANALYSIS OF DEBLOOMED MINERAL PAINT OIL[2]
========+============+================+=====
Sp. Gr. | Iodine No. | Saponification | Acid
| | No. | No.
--------+------------+----------------+-----
.92 | 12 | 4 | 0
========+============+================+=====
[2] Oil of mirbane present, probably as a deblooming agent, or to mask
the odor.
=Pine Oil.= This oil is produced by the redistillation of the heavy,
high boiling point fractions resulting from the steam distillation of
wood turpentine. It is a heavy straw-colored oil, and should be of some
use in the paint and varnish industry, where a high boiling point
solvent with an oxidizing principle is desired. It will probably find
application in the manufacture of Baking Japans, Asphalt Paints and
Enamels. Its oxidizing and solvent values are very high. It has a
distinctive sweet pine smell, which makes it popular in the manufacture
of turpentine substitutes from petroleum spirits.
The writer has examined samples of this material, and the following
appear to be of the best grade:
CONSTANTS OF PINE OILS
==========================+======================+====================
| No. 1 | No. 2
--------------------------+----------------------+--------------------
Color |Straw Color |Light Yellow
Specific Gravity at 15 deg. C.|.934 |.936
Boiling Point |192 deg. C. |202 deg. C.
Distillation |95% distils between |95% distils between
| 192-270 deg. C. | 202-280 deg. C.
Residue on Evaporation |14.34% |14.60%
Polymerization Test |3-2/3% unpolymerized |2-1/2% unpolymerized
| at end of 1/2 hour | at end of 1/2 hour
Flash-Point |72 deg. C. |76 deg. C.
Spot Test |Leaves no grease spot |Same as Pine Oil No.
|but only evaporates |1.
|completely in 24 hours|
==========================+======================+====================
=Turpentine.= By direct fire or steam distillation of the sap drippings
collected in pockets cut into pine trees, there is obtained the
turpentine of commerce. It consists largely of pinene and isomeric
terpenes, and has the property of attracting oxygen, with the formation
of peroxides which stimulate the drying of oils. It is a high-grade
solvent for various gums, and is therefore used in the manufacture of
many lacquers as well as for thinning down oil-gum varnishes.
Public-domain text, read in full here on John Shaqi.
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