Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
=Uniform Conditions.= At a glance it is evident that a decided obstacle
in experimentation on the drying properties of oils is the difficulty in
obtaining identical conditions for comparative purposes. Inasmuch as a
multitude of factors, such as uniformity and homogeneity of the driers
and the oils themselves, intensity and source of light, temperature,
uniformity of application, and many others, play a decisive part in the
siccative tendencies of oils, the resources and ingenuity of the chemist
engaged in the research are severely taxed.
=Oxygen Absorption.= It is a well-known fact that linseed oil, when
applied to a clean surface, such as a glass plate, will undergo
oxidation and take up oxygen to the extent of about 16%, forming a hard,
elastic, non-sticky product which has been called linoxyn. This
material, unlike the oil from which it has been formed, is insoluble in
most solvents. Other oils, such as cottonseed, hemp, rape, olive, etc.,
are more fully satisfied in nature and have not the power to absorb the
amount of oxygen taken up by linseed oil.
In carrying out the following tests, on the drying of oils, a quantity
of pure linseed oil of the following analysis was secured:
Specific gravity at 15 deg. C. 0.934
Acid number 5
Saponification number 191-1/2
Iodine number 188
This oil was distributed into a number of 8-oz. oil sample bottles, and
to a series of these bottles was added varying quantities of a very
concentrated drier made by boiling oil to 400 degrees Fahrenheit in an
open kettle, with the subsequent addition of lead oxide. The amount of
drier added to each bottle varied according to the percentage desired;
being calculated on the lead content of the drier, which was very
accurately determined by analysis.
There was secured in this manner a series of oils containing varying
amounts of lead oxide, and from this lot was selected a certain number
of samples which would be representative and typical of paint vehicles
now found in the market.
Another series of tests were made by combining with a large number of
samples of pure linseed oil as used above, various percentages of a
manganese drier made by boiling oil at 400 deg. F. and incorporating
therewith manganese dioxide.
Still another series of tests were made upon a number of oils into which
were incorporated various small quantities of lead oxide and manganese
oxide together, using the standard driers made in the above manner, all
of which were carefully analyzed to determine their contents.
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