Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
When iron is brought into contact with moisture, currents of electricity
flow over the surface of the iron between points that are relatively
pure and points that contain impurities. These currents stimulate the
natural tendency of the iron to go into solution, and the solution
proceeds with vigor at the positive points. The air which the water
contains oxidizes the iron which has gone into solution, and
precipitates the familiar brown iron rust. Thus water, which acts as an
acid, and air, which acts as an oxidizer, have combined together to
accomplish the downfall of the metal.
[Illustration: Three Photomicrographs of Corroding Steel]
=Inhibition and Stimulation of Rust.= It is obvious that if means could
be devised to stop the solution pressure of iron and make it resistant
to the flow of surface electric currents, rust could be prevented. Such
methods have been devised, and to better illustrate how they operate, an
analogy may be drawn between iron in water and shellac in alcohol.
It is common knowledge that when shellac is placed in alcohol, the
shellac will force itself into solution in the alcohol, and form a
clear, transparent lacquer. If, however, there should be mixed with the
alcohol a quantity of water, it would be found that the shellac could no
longer go into solution, and it would remain in its original condition.
In the same way, if there be placed in water a small quantity of
material, such as soluble chromates, or an alkaline substance like
caustic soda or lime, it will be found that iron will no longer have a
tendency to go into solution in this treated water, but will stay bright
and clean. These materials which prevent the rusting of iron have been
called by Cushman, who first advanced these explanations, "rust
inhibitors," or materials which inhibit rusting. The paint maker,
realizing the importance of these rust inhibitors, is incorporating them
into paints designed for the protection of iron and steel, and the
success which paints of this type have met with from a practical
standpoint is a justification of what was first called the "electrolytic
theory," which suggested their use.
By placing small, brightly polished steel plates into a mush of paint
pigment and water, a determination may be made of the pigment's effect
upon the metal. Some pigments, under such conditions, cause rapid
corrosion of the steel plates. Such pigments are stimulators of
corrosion, on account of acid impurities which they contain, or because
of their effect in stimulating galvanic currents. Many carbonaceous
pigments are of this type. Other pigments have the effect of keeping
bright the steel plates and preventing rust. Such pigments are of the
inhibitive type, and their action is to check or retard the solution
pressure of the iron.
Public-domain text, read in full here on John Shaqi.
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