Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
=The Effects of Moisture.= It might occur to the reader that although
paint pigments, when mixed up with water and brought into contact with
the surface of steel, might show either an inhibitive or stimulative
action, that it is by no means certain that the same tendency will be
exhibited by pigments when they are properly mixed with linseed oil and
laid out as a film upon the surface of steel. In answer to this, it may
be well to state that almost no material used by mankind is absolutely
dry. Linseed oil, as it is pressed from the seed, comes from the cells,
carrying with it a certain small definite percentage of water, and it is
quite certain that even the best linseed oil that goes into use is not
theoretically dry. Everyone knows, of course, that oil and water do not
readily mix and are, in fact, more or less repellent to each other. It
is, however, true that, in spite of this, oils can carry quite a
percentage of water, without the admixture being apparent to the eye. In
addition to this, careful experiments have proved very conclusively that
linseed oil films, even after they have oxidized and hardened, have the
power to a certain extent of absorbing water from the atmosphere. It is,
therefore, safe to say that no linseed oil film in a paint coating is
dry all the time. As a matter of fact, there is abundant evidence to
show that in rainy weather, and, in fact, when the humidity in the air
is high, paint films have absorbed water. As the sun comes out and warms
the paint coating, and the humidity content of the atmosphere falls,
this water to a large extent evaporates out of the film, only to be
taken up again when the weather conditions change. This action may be
likened to a breathing of the paint film, that is to say, an indrawing
of water under humid conditions, followed by an exhaling of water under
dry conditions. With these facts in mind, it must be apparent that
pigments laid out in intimate contact with the surface of steel are
subjected at all times either more or less to the reactions produced by
water contact. Furthermore, as it is a property of water to become
saturated with the gases of the atmosphere, such as oxygen, carbonic and
sulphurous acids, and other impurities, there is present in a protective
paint film at all times the elements necessary to carry on the corrosive
process and reactions.
An outline of Cushman's original research work, upon which has been
based the classification of pigments as inhibitors, stimulators, and
inerts, is clearly presented in his report[38] as Chairman of Committee
U of the American Society for Testing Materials, of which the following
is an excerpt:
[38] Page 73, 1910 Proceedings of the American Society for Testing
Materials.
[Illustration: Ferroxyl Tests on Painted Steel Surfaces. Upper Row
Painted with Stimulative Paints--Lower Row with Inhibitive Paints.]
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account