Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
[Illustration: Water Test on Plates Painted--Except in Center Spot. Left
Hand Plates Painted with Stimulative Paints, Right Hand Plates Painted
with Inhibitive Paints.]
[Illustration: View of Steel Plates Painted with Stimulative Paints,
after Immersion in Ferroxyl Jelly.]
"Three years ago the suggestion was made in a paper presented before the
Tenth Annual Meeting of this Society that the various types of
substances used as pigments in protective coatings might exert a
stimulative or an inhibitive action on the rate and tendency to
corrosion of the underlying metal. It was further suggested on a
theoretical ground that slightly soluble chromates should exert a
protective action when employed as pigments by maintaining the surface
of the iron in a passive condition in case water and oxygen penetrated
the paint film. In view also of the well-known fact that alkalies
inhibit while acids stimulate the corrosion of iron, it was suggested
that the action of more or less pure pigments on iron in the presence of
water should be thoroughly investigated. Two years ago this Committee
invited the co-operation of Committee D-1 (then known as Committee E) in
the investigation, and a special sub-committee representing the two main
committees was appointed.
"The methods and results of the water-pigment tests have previously been
reported and published, and need not be given in detail. Briefly, the
method consisted in immersing samples of steel in water suspensions of
the various pigments and blowing air through the containers for definite
periods of time, the corrosion being measured by the loss in weight
sustained by the test pieces. About fifty pigments which are in more or
less common use for painting steel were purchased in the open market and
distributed among a number of the members of the Committee, who agreed
to carry out the work. Each investigator worked independently of the
others, except that the same general method was followed; the time of
exposure to the corroding action, however, varied in the different
experiments. When the results were compared and analyzed by the
sub-committee, it was felt that the general agreement of the results
obtained by the several investigators was striking and merited further
and more systematic work. As a result of these tests the sub-committee
tentatively divided the pigments into inhibitors, stimulators, and
indeterminates. The word 'indeterminate' was selected after considerable
discussion, because the words 'neutral' or 'inert' already possess a
special meaning as applied to paint technology. The Committee takes this
occasion to emphatically state that in adopting this tentative
classification, the words 'inhibitive' and 'stimulative' as used by them
up to the present time apply only to the results obtained in the water
tests, and the inference that the results obtained have decided which
class the pigment will fall into when made into a paint with the usual
Public-domain text, read in full here on John Shaqi.
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