Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
Another curious feature of these tests was the development of a peculiar
aromatic odor which was given off by the oils upon drying in dry air.
When the oils were dried in moist air, a rank odor resembling propionic
acid was observed, and this led the observer to believe that a reaction
was effected by the absorbed oxygen, that caused the glycerin combined
with the linoleic acid as linolein to split up into evil-smelling
compounds. It has been suggested that the oxygen first attacks the
glycerin, transforming it into carbonic acid, water, and other volatile
compounds, which are eliminated before the oil is dried to linoxyn.
Toch,[3] however, has shown that the drying of linseed oil gives off
only very small percentages of carbon dioxide. Mulder has observed that
in the process of linseed oil being oxidized, glycerin is set free,
which becomes oxidized to formic, acetic, and other acids, while the
acid radicals are converted by oxygen into the anhydrides, from which
they pass by further oxidation into linoxyn.
[3] Toch: The Chem. and Tech. of Mixed Paints, p. 89. D. Van Vostand
Co., N. Y.
=Auto-Oxidation of Oil.= The theory of auto-oxidation of linseed oil has
been very ably treated by Blackler, whose experiments indicated that
during the drying process the slow absorption of oxygen was, at a
critical period, followed by a rapid absorption, which he attributes to
the presence of peroxides. The materials produced by this peroxide
formation may act as catalyzers and accelerate the formation of more
peroxide. Lead and manganese oxides may also be oxidized to peroxides by
the action of oxygen, and in this event might act as very active
catalyzing agents or carriers of oxygen. Blackler's statement, that the
presence of driers do not increase, but have a tendency to decrease the
initial velocity of oxygen absorption, has been confirmed by these
experiments, but it has been noticed throughout the tests that the
driers have an accelerative action at a later period.
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