Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
=Effect of Metals on Drying of Oils.= Some most interesting results were
secured by dipping extremely fine copper gauze into linseed oil, and
then suspending the gauze in the air. The adhesion of the oil to the
copper caused the formation of films between the network, and remarkable
drying action was observed. The copper or any superficial coating of
copper oxide which may have been present on the metal, undoubtedly
affected the result to some extent. It has been found that metallic lead
is even more efficient than copper in this respect, but this may be due
to the action of free acid in the linseed oil, forming lead linoleates,
products that greatly accelerate drying. Another interesting experiment
was made by immersing pieces of gauze cloth in linseed oil. After the
excess oil had been removed, by pressing, the cloth was again weighed to
determine the amount of oil used for the experiment. The increase in
oxygen absorption in this case was very rapid, and the result obtained
confirmed the results in the other experiments.
In order to secure a more evenly distributed state of the oil, tests
were conducted by saturating pieces of stiff blotting papers, and, after
exposure, weighing as usual.
=Influence of Light.= The influence of light on the drying of oils is
unquestionably a potent one. The practical painter knows that a certain
varnish will dry quicker when exposed to the light than when in the
dark.
Chevreul was one of the first pioneers in this field of research to
observe the effects of colored lights on drying, and he claimed that oil
exposed under white glass dried more rapidly than when exposed under red
glass, which eliminates all light of short wave lengths.
Genthe obtained interesting results in the drying of oil submitted to
the effect of the mercury lamp. Oxidation without driers was effected
probably through the formation of peroxides. In commenting on this
subject, Blackler[4] gives a description of the use of the Uveol Lamp,
which is similar to the mercury lamp, but has, instead of a glass casing
which cuts off the valuable rays, a fused-quartz casing which allows
their passage.
[4] M. B. Blackler: "The Use and Abuse of Driers," P. and V. Society,
London, Sept. 9, 1909.
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