Paint Technology and TestsGardner, Henry A. (Henry Alfred)
Science
Paint Technology and Tests
Gardner, Henry A. (Henry Alfred)
Paint
XIV WASHINGTON PAINT TESTS 207
XV CEMENT AND CONCRETE PAINT TESTS 214
XVI STRUCTURAL STEEL PAINT TESTS 220
XVII THE SANITARY VALUE OF WALL PAINTS 252
PAINT TECHNOLOGY
CHAPTER I
PAINT OILS AND THINNERS
=Constants and Characteristics of Oils and Their Effect upon Drying.= An
attempt has been made to give in this chapter a brief summary of the
most important characteristics of those oils finding application in the
paint and varnish industry. For methods of oil analysis, the reader is
referred to standard works on this subject; the analytical constants
herein being given only for comparative purposes.
It is well known that one of the most desirable features of a paint oil
is the ability to set up in a short period to a hard surface that will
not take dust. This drying property is dependent upon the chemical
nature of the oil. If it is an unsaturated compound, like linseed oil,
rapid absorption of oxygen will cause the film to dry rapidly and become
hard. If the oil be of a fully satisfied nature, like mineral oil,
oxygen cannot be taken up to any great extent and drying will not take
place. The various animal and vegetable oils differ in their power of
oxygen absorption to a lesser or greater extent. This difference is
referred to by the chemist in terms of the iodine value. The iodine
value of linseed oil is approximately 190, meaning that one gram of the
oil will take up 190 centigrams of iodine. Oils with high iodine values
have good drying powers, while those with low iodine values are, as a
rule, very slow drying in nature.
For a description of the working and drying properties of various oils
used in paints, see Chapter XIV. The oxygen absorption of various oils
and mixtures is shown in Chapter II.
=Linseed Oil.= The seed of the flax plant which is extensively grown in
North Dakota, Argentine Republic and Russia, contains approximately 36%
of oil which may be obtained by grinding, heating, and expression. Ripe
native seed generally produces a pale oil of little odor; the oil from
Argentine seed often having a greenish tint and an odor resembling
sorghum. While filtering, pressing and ageing will remove considerable
of the ("foots") mucilaginous matter, phosphates, silica, etc., from the
oil, the better grades which are intended for varnish making are often
refined with sulphuric acid. A light colored oil which may be heated
without "breaking" results from this treatment, but such oils are apt to
contain considerable free fatty acid, unless they are washed with alkali
subsequent to the sulphuric acid treatment. On account of its rapid
drying properties and general adaptability for all classes of paints and
varnishes, linseed oil has never been supplanted by any other oil.
Chemically it consists of the glycerides of linoleic, oleic, and
isolinoleic acid, its constitution being responsible for its very high
iodine value.
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