Perfumes and their preparation : $b Containing complete directions for making handkerchief perfumes, smelling-salts, sachets, fumigating pastils; preparations for the care of the skin, the mouth, the hair; cosmetics, hair dyes, and other toilet articlesAskinson, George William
Science
Perfumes and their preparation : $b Containing complete directions for making handkerchief perfumes, smelling-salts, sachets, fumigating pastils; preparations for the care of the skin, the mouth, the hair; cosmetics, hair dyes, and other toilet articles
Askinson, George William
Cosmetics; Perfumes
Some manufacturers who prepare their odors by extraction, may find it
advantageous to make also the bisulphide of carbon necessary for it,
and this is best done in Gérard’s apparatus (Fig. 1). It consists of
a cast-iron cylinder _a_, two metres high and one metre in diameter.
This cylinder is heated on the outer surface in an oven, and two tubes,
_c_ and _d_, are attached to it. Tube _d_ is connected by _e_ with
the hemispherical vessel _b_ which is connected by the tube _i_ with
the condenser _mlk_. The condenser is formed of three cylinders made
of sheet zinc which are surrounded with cold water. The condensed
liquid escapes into the vessel _p_, while the gaseous products pass
through _n_ into the chimney. The cylinder _a_ is filled with about
1,500 pounds of charcoal or coke in small pieces, after which it is
closed and all tubes are carefully luted with clay; _a_ is then heated
to a strong red heat and at intervals of three minutes 3 pounds of
sulphur are thrown in through _c_. In twenty-four hours, by the use of
478 pounds of sulphur, 568 pounds of crude bisulphide of carbon are
obtained; a portion of the sulphur distils over uncombined into the
vessel _b_.
[Illustration: FIG. 1.]
The crude bisulphide of carbon contains about twelve per cent of
sulphur and other combinations in solution and is redistilled at
exactly 48° C. (118.4° F.) in a steam-heated apparatus with a long exit
tube cooled with ice below and water above. In order to obtain the
bisulphide of carbon absolutely pure, which is essential to render it
suitable for extraction, it is again distilled at the same temperature,
with the addition of two per cent of palm oil. As the vapors of
bisulphide of carbon are injurious to the organism, the vessels
containing it must always be kept well closed.
B. Chemical Products used for the Preparation of Perfumes.
Among all the substances belonging under this head, there is one
which plays a prominent part in the manufacture of most perfumes. In
handkerchief perfumes it is one of the most important substances, as
it forms not only the greatest bulk, but the perfection of the perfume
depends upon its quality. This substance is—
ALCOHOL,
also called spirit of wine; French, esprit de vin; the well-known
combustible liquid formed by the alcoholic fermentation of sugar,
which is made on a large scale in extensive distilleries. Alcohol is a
thin, mobile liquid with an aromatic odor. The usual “strong” alcohol
of the market contains about ninety-four per cent of absolute alcohol
by volume. This has a specific gravity of 0·820. Its boiling-point is
78·2° C. (172·40 F.), and it congeals at a very low temperature, below
-100° C. Alcohol possesses great solvent power for resins, balsams, and
essential oils.
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