Perfumes and their preparation : $b Containing complete directions for making handkerchief perfumes, smelling-salts, sachets, fumigating pastils; preparations for the care of the skin, the mouth, the hair; cosmetics, hair dyes, and other toilet articles — John Shaqi
Perfumes and their preparation : $b Containing complete directions for making handkerchief perfumes, smelling-salts, sachets, fumigating pastils; preparations for the care of the skin, the mouth, the hair; cosmetics, hair dyes, and other toilet articlesAskinson, George William
Science
Perfumes and their preparation : $b Containing complete directions for making handkerchief perfumes, smelling-salts, sachets, fumigating pastils; preparations for the care of the skin, the mouth, the hair; cosmetics, hair dyes, and other toilet articles
Askinson, George William
Cosmetics; Perfumes
These properties, however, belong only to the commercial stronger or
so-called “druggists’ alcohol,” and more particularly to a very pure
quality of it, as free as possible from fusel-oil compounds, known as
cologne spirit. As absolute alcohol is also necessary for the purposes
of perfumery, we shall briefly describe its preparation.
In order to make absolute alcohol, sulphate of copper is heated in a
retort until it has changed into a white powder. After the powder has
cooled in the covered retort, it is at once introduced into a large
glass bottle; over it is poured the strongest obtainable alcohol (96%
Tralles) which must be free from fusel oil; then the bottle is closed
air-tight and repeatedly shaken. The sulphate of copper which has lost
its water of crystallization by the heat reabsorbs it from the alcohol
and again becomes blue and crystalline. Generally four pounds of
sulphate of copper are used for ten quarts of alcohol; when white burnt
sulphate of copper after long contact with alcohol still remains white,
the alcohol is proved to be practically anhydrous (it may still contain
about two per cent of water).
Larger quantities of absolute alcohol are made in a copper still
containing fused anhydrous chloride of calcium in small pieces. The
apparatus is closed and alcohol of 94 to 95% is poured in through a
tubulure. The mixture often grows so warm that the alcohol begins to
pass over, so that but little heat need be applied to make the absolute
alcohol distil over.
Absolute alcohol obtained in this way—for by repeated distillation
we get at most an alcohol of 96%—abstracts water from the air with
avidity; hence it must be preserved in air-tight vessels which should
contain a small amount of anhydrous sulphate of copper.
[Illustration: FIG. 2.]
Strong commercial alcohol contains varying amounts of water—from four
to twenty parts by volume (96 to 80% alcohol); at the present time,
however, it is always customary for dealers in this country to supply
the officinal alcohol of 94%, when “strong alcohol” is called for.
Its strength is measured by an areometer which sinks in proportion to
the purity of the alcohol; the alcoholometer of Tralles or volumeter
shows at once on its scale how many parts by volume of absolute
alcohol (volume per cent) are contained in 100 volumes of alcohol. The
adjoining figure (Fig. 2) shows Tralles’ alcoholometer, with the vessel
in which the test is made. The readings of the instrument, however,
are correct only at a temperature of 15·6° C. (60° F.), the so-called
normal temperature; at a higher or lower point they must be corrected
according to the tables appended.
At temperatures below the normal, the amount of alcohol is greater than
the areometer indicates, hence a percentage must be added; at higher
temperatures a percentage must be deducted.
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