Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
The methods of preparation of oxide reds vary slightly in detail
according to the material from which they are made, but the general
features of the processes are almost identical and eminently simple.
The principal sources are impure native oxides of iron, such as the
ochres, various waste liquors containing iron salts in solution, and
copperas (protosulphate of iron).
(1) Native oxides. The iron present in the ochres and similar native
earths exists in the form of hydrated oxide, and has a brown red
colour. For many purposes this hue is satisfactory, and the preparation
of such a pigment consists simply in grinding the mineral in a wet
mill, subjecting it to levigation till all grit is removed, and drying.
In order to obtain a brighter red from the native oxides they must be
calcined to effect dehydration. This can be accomplished in the most
rudimentary forms of furnace, and many kinds are in use. The colour
produced depends on the degree and duration of the heat to which the
material is exposed, the shade becoming deeper as the roasting is
prolonged or the temperature increased. As no two samples of ochre are
just alike it is impossible to fix a precise time for the length of the
operation, and therefore it is necessary to repeatedly draw samples in
order to judge of the progress of the dehydration and development of
the colour desired. When the requisite shade is attained, the charge is
drawn and allowed to cool.
(2) Waste Products. The pyrites cinders from sulphuric acid works
afford an abundance of oxide of iron. When the pyrites has contained
no copper, the cinders merely require grinding and levigating, the
iron being present as oxide. But when the pyriteshas been treated
for the recovery of the copper, by a second roasting with salt, the
liquors contain the iron as chloride and sulphate, and lime has to be
added to precipitate the oxide. This last is dried and calcined in the
same manner as the native oxides, and grinding and levigation can be
dispensed with.
The liquors from galvanising works contain acid sulphate of iron (green
copperas) in solution. To correct the acidity, more iron is added in
the form of scrap. Then lime or other alkaline substance is introduced
to throw down the iron as oxide, and this last is filtered out, dried,
and calcined in the usual way.
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