Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
To rapidly carry on the chemical action, the chemical agents should
be well diffused and commingled throughout each other, and the blue
lead should be so exposed as to be open to their attack on all parts
of its surface equally, and all should be at, and kept at, a proper
temperature and a proper degree of humidity. Too dry a heat prevents
the process of conversion. Too moist an atmosphere wastes the materials
and arrests their action. The conditions, therefore, which are most
favourable will be a certain humid atmosphere of well diffused and
commingled vapours or gases, acting on metallic lead exposed to them
under the physical conditions described, and at a temperature between
110° and 135° F.
These favourable conditions can be further augmented by certain
electrical arrangements in connection with them.
Again, in the sources from which the carbonic acid is derived, and
in the arrangement of the apparatus for applying the carbonic acid,
favourable and unfavourable conditions can be imported. Thus, by using
paraffin, petroleum, benzine, or light oil of paraffin or petroleum,
or similar carbonaceous substances free from sulphur, or mixtures of
such carbonaceous substances either alone or mixed with air or other
oxidising substance, comparatively pure carbonic acid may be furnished
without at the same time producing any objectionable compounds.
As a result of his researches and experiments, Prof. Gardner has
proposed (Eng. Pat. 1882, No. 731) certain improvements in the method
of converting blue lead into white lead, in the apparatus employed,
and in the method of making and applying the carbonic acid used in the
process. Some of these improvements are applicable to the open stack or
chamber process, while others relate to closed chambers.
Preferably, for the conversion of blue lead into white lead, Prof.
Gardner adopts a closed, but not air-tight, chamber. This chamber is
ventilated or relieved so as to enable the incoming gases and vapours
to enter it without hindrance, and to escape by means of an exit valve
and pipe, or an exit shaft, connected with the chamber, communicating
with the exterior air, and regulated by a valve or damper. The gases
and vapours within the chamber can find their way out by this exit
shaft only, by slight pressure on expansion from within the chamber;
thus the interior of the chamber is preserved from disturbance, by
preventing the formation of currents within its atmosphere, and yet a
perfect circulation of the gases and vapours is kept up.
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