Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
It is well known that we have in electricity a most powerful agent
by which to effect the chemical combination of various substances on
the one hand, or on the other, by its means to break up and disrupt
a chemical compound. Professor Gardner’s main principle of action in
his new process is founded upon these facts, and he takes advantage
of electrical power to cause the combination of the lead with the
necessary elements to build up white lead in his chambers. He either
employs electrical discharges to energise and render active in their
chemical affinities the various materials engaged, or he so disposes
of them as to form an electric or galvanic combination in the chamber.
In the latter arrangement the chamber and its contents represent a
gas battery on an extensive scale. In practice he prefers the latter
plan; it is more simple, more manageable in the hands of the ordinary
workmen. The original plan was to have graphite or graphitic carbon
plates or supports for the buckles or gratings of lead within the
converting chamber. These carbon plates and the lead to be converted,
were so placed as to form a collection of galvanic “couples” or
“pairs,” and in this condition were submitted to the gases entering
the chamber from without. It will be understood that various modes of
arrangement would occur without departing from the principle concerned.
In practice this method answered very well, but presently a
difficulty arose; not only were the graphitic carbon or graphitic
plates expensive, but they were easily broken, and became friable
in use. Carbon plates of an especial kind were manufactured to meet
these failures and remedy these defects, not without success, but
still open to objection. In looking round for some substitute to
replace the carbon, two points were to be kept in view, to seek some
electro-negative to lead like the carbon, and some electro-conductive
like it, and some material that would bear rough handling such as
workmen give, and be practically convenient in its adaptation to a
working chamber.
Gold or platinum would excel in these particulars, but there are
considerations which debar their use. Pure tin presented itself, and
tin was tried with great success. Tin would at first be thought,
on account of its close electrical relationship to lead, far from
favourable to the purpose. Graphite or carbon would appear far more
suitable. Practice pronounced the tin to act as efficiently as carbon.
This may at first seem contradictory and strange, but if we consider
that while the carbon is certainly more highly electro-negative to
lead than tin, yet the tin is the more conductive, and offers the less
resistance to the electric current of the two; in this manner the tin
compensates by its conductive power all it may lack, as compared with
carbon, in electrical energy when coupled up with lead.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account