Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Tin plate is now used as the electric-negative element in the chamber
of the Gardner plan. Tin plate means pure tin. Ingot tin is rolled out
into plates, the bottom of the chamber is covered with this pure tin
plate, so are the bearers and the shelves, or supports which are to
hold the lead during its conversion. Tin pipes and tin fittings, which
resist the action of acetic acid, are also used to conduct the gases to
the chamber to carry on the converting operation, and to preserve the
product from any source of discoloration.
When a chamber is prepared for the converting operation, the whole of
the lead it contains will be in metallic communication with the tin
supports, and these with the tin covered bottom of the chamber.
The chamber when working is kept at a certain temperature by a steam
coil beneath the floor of the chamber. The process is simple. The lead
buckles or gratings are placed on tin-covered stands, somewhat in form
and make like a dinner-waggon. The whole is hauled up and dipped into
a bath of acetic acid and acetate of lead; it there remains for one or
two minutes, it is then hauled out, drained and lifted bodily through
the top into the chamber. Other stands filled with buckles are so
dipped and so placed till the space of the chamber is fully occupied.
This dipping cleanses the surface of the metal, and when it is exposed
to the air it is speedily coated with a hydrated oxide of lead. This is
the first step in the process of conversion. The chamber when filled is
closed, and its temperature is brought to about 100° F.; then vapour
of acetic acid and vapour of water and air are supplied from without
to the interior of the chamber. This is continued for 15 or 20 hours.
The lead buckles within the chamber will now possess a whitish coating,
consisting of subhydrate and subacetate of lead, and they will present
a uniform colour. Carbonic acid generated in any convenient manner is
next passed into the acid generator; it mixes with the other gases and
vapours, and with them goes on its way to supply the chamber. Speedily
the action of the carbonic acid is observed, the surface lead becomes
quite white and presents the appearance of a snow shower having fallen
within the chamber. The formation of white lead is now speedily
effected. This treatment is continued throughout the space of 13 days;
at the end of this time the supply of acetic acid vapour is stopped,
and the supply of air, steam and carbonic acid is continued, according
as it is desired to obtain white lead rich in oxide or in carbonate.
After a short further period, steam and air only are sent into the
chamber, which is varied in temperature to 120° or 130°F., and lastly
the steam supply is stopped; air alone enters the chamber, which is
kept heated by the coils beneath the floor. The contents of the chamber
are now in a dry state, and the operation is terminated.
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