Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
When litharge is heated with linseed oil, the action is somewhat
similar, the substances formed being acrolein, lead linoleate, and
linoleic acid.
If we consider the action of red lead on trilinolein, we have not
only the formation of these lead linoleates, but an excess of oxygen
available for the oxidation of glycerine to acrolein and acrylic acid,
or to acetic and formic acids.
These equations serve to show the effect of lead and lead oxides in
what may be termed the initiation of the chemical action upon the oil.
Subsequent changes, no doubt, depend upon the conditions which obtain
at the time, notably upon the temperature and upon access of air to the
oil. It is probable that acid linoleates are formed, and that compounds
formed from the polymerisation of linoleic acid result eventually.
Whatever doubt there may be as to the action of lead salts, there can
be none whatever as to that of manganese compounds. In the first place,
manganous oxide is a powerful base, which readily dissolves in oil;
manganic oxide is also readily soluble, yielding fatty acid salts of
manganese, and causing oxidation of glycerine. Manganese borate and
manganese oxalate are both soluble in oil, the former much more readily
than the latter, but they are both salts of little stability at high
temperatures in contact with oils. They both dissolve by the aid of
heat, forming fatty acid salts of manganese. Borate liberates boric
acid under these circumstances, but oxalate yields a mixture of carbon
monoxide and carbon dioxide.
Of manganese oleate and linoleate nothing more may be said than that
both are extremely soluble in oil, and both easily oxidised from
colourless to brown compounds when submitted to the action of air.
The chief adulterants of linseed oil and of boiled oil are cotton-seed
oil, rosin oil, and linoleic acid. Cotton-seed, which is to some extent
a drying oil, can act as such when mixed with linseed, but when added
to olive oil, it behaves as a non-drying oil. In fact, its behaviour
is anomalous, and of such a character that it greatly facilitates its
extensive use as an adulterating material for the more expensive oils.
Rosin oil is a deleterious adulterant, but one which may be more
readily detected than cotton-seed oil. Rosin is added to boiled oil to
hasten its drying; this also is an injurious substance. Of late years
glycerine has become an article of greater value than formerly, and
this may account for the manufacture of linoleic acid and its use as an
adulterant of oleic acid and of linseed oil.
Lastly, it may be mentioned that certain samples of “pale boiled oil”
have been found to contain what is practically a raw oil mixed with
dryers. Although such oils will dry, their efficiency is nothing like
so great as that of an oil “boiled” with a blast of air at a suitable
temperature, and, moreover, such oils are deficient in body.
Public-domain text, read in full here on John Shaqi.
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