Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
In bleaching vegetable oils, it is necessary to consider the nature
of the colouring matters naturally contained in them. These consist
of a mixture in varying proportions of the colouring matters known to
exist in the leaves of plants, but which, in the case of oils, are
derived from the fruit or seeds from which the oils are expressed.
There can be no doubt that these substances are closely allied in
chemical constitution; they all possess an intensely powerful colouring
property, by which is meant that though the colour of some of them may
not be dark, yet a very minute weight is capable of imparting a tint to
a very large quantity of material.
The names of these substances are:--
Xanthophyll--yellow.
Yellow chlorophyll--yellow.
Blue chlorophyll--blue.
Erythrophyll--red.
In some oils only the xanthophyll and yellow chlorophyll are present;
in others, such as olive oil, the yellow and blue chlorophylls occur,
and give the liquid a green tint; while in linseed erythrophyll is
always present with more or less of the yellow and blue chlorophylls,
and some xanthophyll. According to the different proportions of these
colouring matters the oil varies in colour. For instance, linseed oil,
when brown, contains a mixture of erythrophyll with yellow and blue
chlorophylls; when greenish brown, the yellow and blue chlorophylls are
present in somewhat larger proportion, but mixed with erythrophyll;
while, generally speaking, a bright yellow or pale yellow oil contains
xanthophyll only. These substances appear to be combined with the oils,
or to be substances of a fatty nature. They are neither dissolved nor
acted upon by water, nor by acids diluted with water, when naturally
contained in the oils. They are freely soluble in alcohol, and an
alcoholic solution is not only susceptible of being destroyed by the
joint action of air and water, but by very dilute aqueous solutions of
mineral acids, and by acetic acid. In aqueous and alcoholic solutions,
light speedily modifies the blue, and eventually destroys all these
colours. A solution in turpentine of the isolated colouring matters
is also easily destroyed. But, on the other hand, a solution of the
colours in melted paraffin wax is comparatively stable.
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