Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
Zinc hydroxide, copper hydroxide, baryta, potash, and soda easily
combine to form metallic salts with blue chlorophyll, less readily,
though readily enough with yellow chlorophyll, but far less readily
with xanthophyll and erythrophyll. The following facts will serve
to show that this is the case. When a solution of the colouring
matters contained in green leaves is made by extracting dry, but
freshly-gathered, leaves with absolute alcohol, an addition of a
saturated solution of baryta water, to the intensely green extract,
precipitates first the compound of blue chlorophyll with baryta, then a
further addition precipitates the yellow chlorophyll, also as a baryta
salt; but xanthophyll and erythrophyll either remain in solution, or
require a much larger addition of the base in order to be precipitated.
A crystalline compound of blue chlorophyll with soda is comparatively
stable. This substance is, no doubt, formed in green vegetables when
they are boiled in water to which some carbonate of soda has been added
to maintain their fresh appearance. The addition of a small trace
of copper sulphate to peas and to pickles forms a very permanent
copper compound with the colouring matter, which gives an attractive
appearance to these articles. Such being an outline of the chief
chemical properties of the natural colouring matters contained in oils,
the facts mentioned will serve to render the processes for removing the
colour from oils more intelligible than they otherwise would be.
Vegetable oils are decolorised, either partially or completely, by the
application of one of the following processes:--
1. By the action of light, or by the joint action of light and air.
2. By acids.
3. By saponification.
4. By the action of chlorine.
1. By exposing raw linseed oil to the action of sunlight, it slowly
becomes pale in colour, and finally colourless. It is in the highest
degree probable that, as oxygen is absorbed by the oil and acid
substances are thereby produced, these acids effect the destruction of
the colouring matters. In such wise castor oil is bleached.
2. By treating linseed oil with moderately strong sulphuric acid. As
the oil and sulphuric acid are of very different specific gravities, it
is essential that they be very rapidly and thoroughly mixed by violent
agitation. The impurities, such as mucilage and albuminous matters,
are thus deprived of water, and more or less charred, and along with
them the colouring matters are destroyed by the acid. It is essential
for the success of the process that the oil and the acid be not long
in contact without undergoing dilution, otherwise the oil itself may
become charred. It is, however, possible to obtain oil by this process
in a fairly colourless condition, after it has been thoroughly washed
with water and allowed to settle.
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