Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
3. Both rape oil and cotton oil may be rendered of a pale yellow,
and even almost colourless, by a process of partial saponification
with caustic alkali of a suitable strength. The colouring matters are
saponified, and the resulting soap is of a dark yellow or brown colour,
from the colouring matter having combined with the alkali.
4. By the action of chlorine produced in contact with the oil when, for
instance, an aqueous solution of bleaching powder is acidified with a
cheap mineral acid, such as dilute sulphuric. In this case rapid mixing
and violent agitation are essential to the success of the process,
otherwise chlorinised products are retained in the oil, which not only
confer upon it a distinct flavour and odour, but also cause the oil to
solidify with a very moderate lowering of the normal temperature. It is
very questionable whether drying oils can with advantage be submitted
to such treatment.
5. A variety of methods may be merely mentioned, such as treatment with
sulphurous acid, with ferrous sulphate (green vitriol), and potassium
dichromate and sulphuric acid.
6. Lastly, the method of Binks, to which reference will be made farther
on.
Prof. Hartley next gives an account of certain improvements in the
process of oil-boiling, designed with the object of producing a drying
oil absolutely free from lead, and, as compared with ordinary oils,
absolutely free from colour.
The operations have been carried out, on a manufacturing scale, by
Mr. W. E. B. Blenkinsop and himself, and there is no doubt of the
practicability of the process.
The process consists in, first, refining the oil, by the removal
therefrom of water and mucilage; second, boiling and bleaching the oil
at one operation.
It is a fact that water and mucilage can be removed from linseed oil by
the action of certain dehydrating substances and solutions of metallic
salts, as, for instance, by alum, by strong sulphuric acid, and by a
solution of zinc chloride.
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