Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
the cobalt ore is first spalled and hand-picked to remove the ores
of foreign metals which are associated with it; and then reduced to
a very fine state in an edge runner or mortar mill, and freed from
earthy impurities by washing. The concentrated ore is then dried and
dead-roasted in small charges at a time (about 4 cwt.) in a specially
designed reverberatory furnace such as shown in Fig. 12, of which _a_
is the hearth on which the ore is spread; _b_, the fireplace, the
products of combustion from which pass over the ore on the hearth, and
thence into the flues _c_, which repeatedly circle round the furnace
so as to provide abundant opportunity for the arsenious oxide derived
from the combustion (oxidation) of the arsenic in the ore to condense;
this highly poisonous arsenious oxide is collected in a solid form from
the flues at convenient intervals by means of the doors _d_. The ore
is charged and discharged at the door _e_. The roasting should not be
carried to such a point that the whole of the sulphur and arsenic are
removed when making smalts, as by leaving a portion of these substances
in the ore at this stage, the ultimate purification is better
accomplished.
The next stage is to fuse the roasted ore with potash and silica so
as to form a blue glass. The proportions in which the ingredients are
mixed depend upon the depth of colour in the zaffre operated upon and
the tint desired in the finished smalts; hence it is always determined
by a preliminary experiment, and is then most carefully adhered to,
each material being accurately weighed out. Only the best potash can
be used, as it must be quite free from soda, and iron or other metal;
the effect of soda is to render the blue greenish tinted. Quartz
affords the requisite silica, and is hand-picked to ensure freedom from
alumina, iron, and lime, which import dullness into the colour, and
then ground to a fine powder in an edge runner mill. The duly weighed
quantities of the several ingredients are intimately mixed in wooden or
cement lined vessels, so as to preclude the possibility of any metallic
iron finding its way in; and as a further protection against this risk
a little white arsenic is often added so that the iron may be carried
down in the regulus which is formed during the fusion in the crucible.
These crucibles are of refractory earthenware quite free from lime,
and measure about 18 inches across at top, gradually diminishing to 14
inches at bottom, so that an ordinary charge is about ¾ cwt. They are
placed in rows in a furnace which generally bears a close resemblance
to a glass furnace, the operation being very similar. The form of
furnace common in Saxony, where most of the smalts is made, is shown in
Fig. 13. By means of a series of openings a in the walls of the furnace
the pots _b_ are introduced on to the hearth of the furnace, whereupon
the openings _a_ are bricked up again and remain closed during the
operation. The ingredients are charged into the pots _b_
Public-domain text, read in full here on John Shaqi.
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