Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
and these, in the absence of iron, would decompose some of the cyanide
of potash into sulphocyanate, thereby causing a loss of cyanogen so
far as yellow prussiate is concerned; and secondly, because potassium
bisulphide has a very corrosive action on the iron pot in which the
fusion takes place. When iron is present it readily decomposes any
alkaline sulphides, thereby preventing formation of sulphocyanate, and
being itself converted into iron sulphide, which is again changed into
prussiate by the action of the aqueous cyanide.
Pear-shaped iron pots were formerly used for fusing the raw materials.
The arrangement now generally adopted in large English works consists
of a series of iron pots almost hemispherical in shape, set in
brickwork, and each heated by a separate fire and circular flue. These
vessels are closed by iron lids, with apertures for the admittance of
animal matters, the aperture being at once closed by a slide after each
addition. Through every lid there passes a vertical spindle, carrying a
set of blades for mixing the materials, and set in motion by a suitable
shaft worked by steam power. Instead of the ordinary iron pots,
reverberatory furnaces are often employed, especially in Germany. The
reason for this preference is, that ordinary iron vessels are worn out
in a comparatively short time, the destructive action being greatest on
the under surface of the muffle. A much larger quantity of raw material
can also be operated upon at one time if a reverberatory furnace be
used. The mode of procedure depends to some extent upon the condition
of the organic materials employed. If fresh, the muffle or furnace must
be left open, so as to permit the mixture to be well and frequently
stirred, and additions to be made at intervals until eventually
ammonia ceases to be evolved. The furnaces are arranged in such a
manner that when the carbonate of potash has once become fused the
doors of the fire-place may be shut, and no fresh firing is required
during the introduction of the animal matters. The molten mass is kept
well stirred by means of a thick iron bar, suspended by a chain, and
fixed in an aperture in the side of the furnace. By the use of this
arrangement the stirring is much more easily and thoroughly effected
than is the case with the old fashioned pots. Ordinary reverberatory
furnaces cannot be used for the fusion, because the silica in the
hearth would combine with the potash to form silicate of potash.
Gas generators with air blast are now sometimes employed instead of
ordinary fuel in the manufacture of yellow prussiate of potash. Several
advantages are gained by operating in this manner, especially that of
permitting the regulation of temperature and the admission of oxygen,
so as to obtain an ordinary, a neutral, or a reducing flame, according
to requirements. In the preparation of the “metal,” for every 100
parts of pearlash from 100 to 125 parts of fresh animal substances are
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