Pigments, Paint and Painting: A practical book for practical menTerry, George
Science
Pigments, Paint and Painting: A practical book for practical men
Terry, George
Paint; Painting, Industrial; Pigments
(1) The “metal” is made by fusing animal matters with pearlash, almost
invariably with the addition of iron scrap. The animal substances are
sometimes used in their original condition, whilst sometimes they are
previously charred. Generally speaking, however, a judicious mixture
of the fresh and charred materials has been found to give the best
results. The charcoal which is left on carbonising animal matters
contains a certain amount of nitrogen, decreasing in proportion as the
temperature rises; but a smaller quantity of charcoal is also thereby
produced. For example: 100 parts of rags carbonised at a certain
temperature left 75 parts charcoal containing 12 per cent. of nitrogen,
while the same rag carbonised at a higher temperature yielded 25 parts
of charcoal, which contained only 2 per cent. of nitrogen. The animal
matters employed should not leave much ash on ignition, as this would
both thicken the mass and decompose a portion of the potash. In this
respect sand is specially objectionable, for on ignition 1 part will
decompose 2 of pearlash, owing to formation of silicate of potash. It
is not necessary that the pearlash should be quite pure; in fact, a
certain proportion of sulphate is stated to be useful, as it is changed
into sulphide by ignition with the carbonaceous materials.
The theory of the formation of yellow prussiate of potash may be
briefly stated as follows: The carbonate and sulphate of potash
react with the carbon, nitrogen, and iron, forming in the first
instance sulphide of potassium, which afterwards converts the iron
into sulphide, whilst potassium cyanide is simultaneously produced.
It should be here explained that ferrocyanide of potassium (yellow
prussiate) is not formed during the ignition of the above mentioned
materials, but results from the lixiviation of the fused mass with
water, when the cyanide of potassium and iron sulphide decompose
each other, producing ferrocyanide and sulphide of potassium. It is
quite obvious that even if any ferrocyanide were produced during the
process of fusion, it would almost immediately be decomposed, at the
intense heat to which the mass is subjected, into potassium cyanide,
iron carbide, and nitrogen gas. If any doubt were felt on this point,
the experiments of Liebig conclusively prove that the formation of
ferrocyanide takes place on dissolving the ignited mass in water, but
not previously. Liebig found that if the fused mixture be allowed
to cool, and then treated with moderately strong alcohol, potassium
cyanide alone is extracted, and the residue when dissolved in water
no longer yields ferrocyanide. As ferrocyanide is not formed during
the process of fusion, the presence of iron in the preliminary stages
may appear superfluous; but such is not the case. The presence of iron
is necessary for two reasons, firstly, because the sulphate of potash
which is generally present is converted into sulphide and bisulphide,
Public-domain text, read in full here on John Shaqi.
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